Synthesis of 5- to 8-membered cyclic carbonates from diols and CO₂: A one-step, atmospheric pressure and ambient temperature procedure

6-, 7- and 8-membered ring cyclic carbonates are of particular interest as monomers for ring-opening polymerisation towards more sustainable polymers. They are traditionally synthesised from diols and phosgene derivatives, and while alternative CO₂ methods exist to make 5- and 6-membered cyclic carbonates, there is no report of the synthesis of 7- and 8-membered cyclic carbonates made directly from CO₂. Herein we report an efficient one-pot synthesis of cyclic carbonates which uses diols, CO₂, tosyl chloride and mild bases (NEt₃ or TMP), under ambient temperature and 1 atm of CO₂ pressure. Fifteen cyclic carbonates were synthesised, including twelve known monomers, and the first examples of 7- and 8-membered cyclic carbonates made using CO₂.