Synthesis, molecular structure and electrochemistry of pentagonal bipyramidal nickel(II) complexes of quinquedentate macrocylic ligand incorporating a 2,2′:6′,2″-terpyridyl moiety

Edwin C. Constable; Jack Lewis; Michael C. Liptrot; Paul R. Raithby; Martin Schröder

doi:10.1016/S0277-5387(00)83918-2

Synthesis, molecular structure and electrochemistry of pentagonal bipyramidal nickel(II) complexes of quinquedentate macrocylic ligand incorporating a 2,2′:6′,2″-terpyridyl moiety

Edwin C. Constable, Jack Lewis, Michael C. Liptrot, Paul R. Raithby, Martin Schröder

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [Ni(L)(EtOH)₂](BF₄)₂ involving the quinquedentate terpyridyl macrocyclic ligand L is reported; the electrochemical reduction of such complexes yields, in solution, d⁹ nickel(I) species.

Original language	English
Pages (from-to)	301-302
Number of pages	2
Journal	Polyhedron
Volume	2
Issue number	4
DOIs	https://doi.org/10.1016/S0277-5387(00)83918-2
Publication status	Published - 31 Dec 1983

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(00)83918-2

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Synthesis, molecular structure and electrochemistry of pentagonal bipyramidal nickel(II) complexes of quinquedentate macrocylic ligand incorporating a 2,2′:6′,2″-terpyridyl moiety. / Constable, Edwin C.; Lewis, Jack; Liptrot, Michael C. et al.
In: Polyhedron, Vol. 2, No. 4, 31.12.1983, p. 301-302.

Research output: Contribution to journal › Article › peer-review

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abstract = "The synthesis and single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [Ni(L)(EtOH)2](BF4)2 involving the quinquedentate terpyridyl macrocyclic ligand L is reported; the electrochemical reduction of such complexes yields, in solution, d9 nickel(I) species.",

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AU - Lewis, Jack

AU - Liptrot, Michael C.

AU - Raithby, Paul R.

AU - Schröder, Martin

PY - 1983/12/31

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AB - The synthesis and single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [Ni(L)(EtOH)2](BF4)2 involving the quinquedentate terpyridyl macrocyclic ligand L is reported; the electrochemical reduction of such complexes yields, in solution, d9 nickel(I) species.

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Synthesis, molecular structure and electrochemistry of pentagonal bipyramidal nickel(II) complexes of quinquedentate macrocylic ligand incorporating a 2,2′:6′,2″-terpyridyl moiety

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