Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]

A Toure; C A K Diop; L Diop; U Russo; M F Mahon; K C Molloy

doi:10.1016/j.crci.2006.09.020

Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]

A Toure, C A K Diop, L Diop, U Russo, M F Mahon, K C Molloy

Department of Chemistry

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Abstract

SnCl4-, SnCl5-- and SnCl62--containing compounds have been synthesized, and their Mossbauer and infrared spectroscopic studies undertaken. The environment around the tin centre is octahedral in all compounds. Infrared and Mossbauer spectroscopies show that the thiocyanate anion acts as a N-donor ligand. The X-ray structure determination of [C6H5COCH2NH3](2)[SnCl6] has also been reported; this structure consists of octahedral SnCl62- anions connected together into layers via hydrogen bonds between the chlorine and the hydrogen atoms of the NH3+ groups of the C6H5COCH2NH3+ cations.

Original language	English
Pages (from-to)	552-557
Number of pages	6
Journal	Comptes Rendus Chimie
Volume	10
Issue number	6
DOIs	https://doi.org/10.1016/j.crci.2006.09.020
Publication status	Published - 2007

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ID number: ISI:000247909700016

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Toure, A., Diop, C. A. K., Diop, L., Russo, U., Mahon, M. F., & Molloy, K. C. (2007). Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]. Comptes Rendus Chimie, 10(6), 552-557. https://doi.org/10.1016/j.crci.2006.09.020

Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]. / Toure, A; Diop, C A K; Diop, L et al.
In: Comptes Rendus Chimie, Vol. 10, No. 6, 2007, p. 552-557.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]",

abstract = "SnCl4-, SnCl5-- and SnCl62--containing compounds have been synthesized, and their Mossbauer and infrared spectroscopic studies undertaken. The environment around the tin centre is octahedral in all compounds. Infrared and Mossbauer spectroscopies show that the thiocyanate anion acts as a N-donor ligand. The X-ray structure determination of [C6H5COCH2NH3](2)[SnCl6] has also been reported; this structure consists of octahedral SnCl62- anions connected together into layers via hydrogen bonds between the chlorine and the hydrogen atoms of the NH3+ groups of the C6H5COCH2NH3+ cations.",

author = "A Toure and Diop, {C A K} and L Diop and U Russo and Mahon, {M F} and Molloy, {K C}",

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T1 - Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]

AU - Toure, A

AU - Diop, C A K

AU - Diop, L

AU - Russo, U

AU - Mahon, M F

AU - Molloy, K C

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PY - 2007

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N2 - SnCl4-, SnCl5-- and SnCl62--containing compounds have been synthesized, and their Mossbauer and infrared spectroscopic studies undertaken. The environment around the tin centre is octahedral in all compounds. Infrared and Mossbauer spectroscopies show that the thiocyanate anion acts as a N-donor ligand. The X-ray structure determination of [C6H5COCH2NH3](2)[SnCl6] has also been reported; this structure consists of octahedral SnCl62- anions connected together into layers via hydrogen bonds between the chlorine and the hydrogen atoms of the NH3+ groups of the C6H5COCH2NH3+ cations.

AB - SnCl4-, SnCl5-- and SnCl62--containing compounds have been synthesized, and their Mossbauer and infrared spectroscopic studies undertaken. The environment around the tin centre is octahedral in all compounds. Infrared and Mossbauer spectroscopies show that the thiocyanate anion acts as a N-donor ligand. The X-ray structure determination of [C6H5COCH2NH3](2)[SnCl6] has also been reported; this structure consists of octahedral SnCl62- anions connected together into layers via hydrogen bonds between the chlorine and the hydrogen atoms of the NH3+ groups of the C6H5COCH2NH3+ cations.

U2 - 10.1016/j.crci.2006.09.020

DO - 10.1016/j.crci.2006.09.020

M3 - Article

SN - 1631-0748

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JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

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ER -

Synthesis, infrared, Raman and Mossbauer spectroscopic studies of SnCln (n=4, 5) with Ph3PO, Ph3AsO and R(4)ZX (R = Me, Et; Z = N, P and X = Cl, Br, SCN). Molecular structure of [C6H5COCH2NH3](2)[SnCl6]

Abstract

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