Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate

C A K Diop; S Bassene; M Sidibe; A D Sarr; L Diop; K C Molloy; M F Mahon; R A Toscano

Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate

C A K Diop, S Bassene, M Sidibe, A D Sarr, L Diop, K C Molloy, M F Mahon, R A Toscano

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (SciVal)

Abstract

The crystal and spectroscopic characterization of three triorganotin derivatives, namely [Ph3SnO3SPh](n), [Me3SnO2P(OH)(Me)](n) and [Me3SnO2As(OH)(Ph)](n) are reported. In each case the structure consists of one- or three-dimensional, polymeric chains involving R3Sn (R = Me, Ph) moieties axially bridged through either benzenesulphonato, methylphosphonato or phenylarsonato ligands. The tin atoms in each case are in a trans-O2SnC3 trigonal bipyramidal environment. Hydrogen bonds ensure the compactness of the structures of the methylphosphonato and phenylarsonato derivatives.

Original language	English
Pages (from-to)	683-689
Number of pages	7
Journal	Main Group Metal Chemistry
Volume	25
Issue number	11
Publication status	Published - 2002

Bibliographical note

ID number: ISI:000179594200007

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title = "Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate",

abstract = "The crystal and spectroscopic characterization of three triorganotin derivatives, namely [Ph3SnO3SPh](n), [Me3SnO2P(OH)(Me)](n) and [Me3SnO2As(OH)(Ph)](n) are reported. In each case the structure consists of one- or three-dimensional, polymeric chains involving R3Sn (R = Me, Ph) moieties axially bridged through either benzenesulphonato, methylphosphonato or phenylarsonato ligands. The tin atoms in each case are in a trans-O2SnC3 trigonal bipyramidal environment. Hydrogen bonds ensure the compactness of the structures of the methylphosphonato and phenylarsonato derivatives.",

author = "Diop, \{C A K\} and S Bassene and M Sidibe and Sarr, \{A D\} and L Diop and Molloy, \{K C\} and Mahon, \{M F\} and Toscano, \{R A\}",

note = "ID number: ISI:000179594200007",

year = "2002",

language = "English",

volume = "25",

pages = "683--689",

journal = "Main Group Metal Chemistry",

issn = "0334-7575",

publisher = "De Gruyter",

number = "11",

}

TY - JOUR

T1 - Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate

AU - Diop, C A K

AU - Bassene, S

AU - Sidibe, M

AU - Sarr, A D

AU - Diop, L

AU - Molloy, K C

AU - Mahon, M F

AU - Toscano, R A

N1 - ID number: ISI:000179594200007

PY - 2002

Y1 - 2002

N2 - The crystal and spectroscopic characterization of three triorganotin derivatives, namely [Ph3SnO3SPh](n), [Me3SnO2P(OH)(Me)](n) and [Me3SnO2As(OH)(Ph)](n) are reported. In each case the structure consists of one- or three-dimensional, polymeric chains involving R3Sn (R = Me, Ph) moieties axially bridged through either benzenesulphonato, methylphosphonato or phenylarsonato ligands. The tin atoms in each case are in a trans-O2SnC3 trigonal bipyramidal environment. Hydrogen bonds ensure the compactness of the structures of the methylphosphonato and phenylarsonato derivatives.

AB - The crystal and spectroscopic characterization of three triorganotin derivatives, namely [Ph3SnO3SPh](n), [Me3SnO2P(OH)(Me)](n) and [Me3SnO2As(OH)(Ph)](n) are reported. In each case the structure consists of one- or three-dimensional, polymeric chains involving R3Sn (R = Me, Ph) moieties axially bridged through either benzenesulphonato, methylphosphonato or phenylarsonato ligands. The tin atoms in each case are in a trans-O2SnC3 trigonal bipyramidal environment. Hydrogen bonds ensure the compactness of the structures of the methylphosphonato and phenylarsonato derivatives.

M3 - Article

SN - 0334-7575

VL - 25

SP - 683

EP - 689

JO - Main Group Metal Chemistry

JF - Main Group Metal Chemistry

IS - 11

ER -

Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate

Abstract

Bibliographical note

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