TY - JOUR
T1 - Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3
AU - Diop, T.
AU - Diop, L.
AU - Molloy, K.C.
AU - Kociok-Kohn, Gabriele
AU - Fall, D.
PY - 2012/9
Y1 - 2012/9
N2 - The title compound, [(CH)CH]NH ·[(PhPOH)SnPh]-, has been synthesised and its structure determined by spectroscopies (IR, RMN and Mössbauer) and single crystal X-ray crystallography. The Mössbauer spectroscopy data for the title compound (QS = 3.50 mm s ) are in accordance with the trans OSnC geometry at tin atom. The SnPh residue is axially coordinated by two monodentate [PhPO H]- anions, leading to a trigonal-bipyramidal geometry around the tin atom. The anions [(PhPOH)SnPh]- are linked by pairs of O-H⋯O interaction, forming an infinite chain. In the crystal, neighbouring chains are linked by hydrogen bonds N-H⋯O via the cation [(CH)CH]NH forming a three-dimensional network.
AB - The title compound, [(CH)CH]NH ·[(PhPOH)SnPh]-, has been synthesised and its structure determined by spectroscopies (IR, RMN and Mössbauer) and single crystal X-ray crystallography. The Mössbauer spectroscopy data for the title compound (QS = 3.50 mm s ) are in accordance with the trans OSnC geometry at tin atom. The SnPh residue is axially coordinated by two monodentate [PhPO H]- anions, leading to a trigonal-bipyramidal geometry around the tin atom. The anions [(PhPOH)SnPh]- are linked by pairs of O-H⋯O interaction, forming an infinite chain. In the crystal, neighbouring chains are linked by hydrogen bonds N-H⋯O via the cation [(CH)CH]NH forming a three-dimensional network.
UR - http://www.scopus.com/inward/record.url?scp=84870955766&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1515/mgmc-2012-0023
U2 - 10.1515/mgmc-2012-0023
DO - 10.1515/mgmc-2012-0023
M3 - Article
AN - SCOPUS:84870955766
SN - 0792-1241
VL - 35
SP - 99
EP - 102
JO - Main Group Metal Chemistry
JF - Main Group Metal Chemistry
IS - 3-4
ER -