Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

T. Diop, L. Diop, K.C. Molloy, Gabriele Kociok-Kohn, D. Fall

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Abstract

The title compound, [(CH)CH]NH ·[(PhPOH)SnPh]-, has been synthesised and its structure determined by spectroscopies (IR, RMN and Mössbauer) and single crystal X-ray crystallography. The Mössbauer spectroscopy data for the title compound (QS = 3.50 mm s ) are in accordance with the trans OSnC geometry at tin atom. The SnPh residue is axially coordinated by two monodentate [PhPO H]- anions, leading to a trigonal-bipyramidal geometry around the tin atom. The anions [(PhPOH)SnPh]- are linked by pairs of O-H⋯O interaction, forming an infinite chain. In the crystal, neighbouring chains are linked by hydrogen bonds N-H⋯O via the cation [(CH)CH]NH forming a three-dimensional network.
Original languageEnglish
Pages (from-to)99-102
Number of pages4
JournalMain Group Metal Chemistry
Volume35
Issue number3-4
DOIs
Publication statusPublished - Sep 2012

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Mossbauer spectroscopy
Tin
Negative ions
Crystal structure
Atoms
Geometry
X ray crystallography
Infrared spectroscopy
Hydrogen bonds
Positive ions
Single crystals
Crystals

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Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3. / Diop, T.; Diop, L.; Molloy, K.C.; Kociok-Kohn, Gabriele; Fall, D.

In: Main Group Metal Chemistry, Vol. 35, No. 3-4, 09.2012, p. 99-102.

Research output: Contribution to journalArticle

Diop, T. ; Diop, L. ; Molloy, K.C. ; Kociok-Kohn, Gabriele ; Fall, D. / Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3. In: Main Group Metal Chemistry. 2012 ; Vol. 35, No. 3-4. pp. 99-102.
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AU - Fall, D.

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AB - The title compound, [(CH)CH]NH ·[(PhPOH)SnPh]-, has been synthesised and its structure determined by spectroscopies (IR, RMN and Mössbauer) and single crystal X-ray crystallography. The Mössbauer spectroscopy data for the title compound (QS = 3.50 mm s ) are in accordance with the trans OSnC geometry at tin atom. The SnPh residue is axially coordinated by two monodentate [PhPO H]- anions, leading to a trigonal-bipyramidal geometry around the tin atom. The anions [(PhPOH)SnPh]- are linked by pairs of O-H⋯O interaction, forming an infinite chain. In the crystal, neighbouring chains are linked by hydrogen bonds N-H⋯O via the cation [(CH)CH]NH forming a three-dimensional network.

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