Synthesis and X-Ray structure analysis of 13,17-bis(2-methoxycarbonylethyl) -12,18-bis(methoxycarbonylmethyl)-2,2,8,8,20-pentamethylisobacteriochlorin

Colin L. Gibson; Michael J. Doyle; Paul R. Raithby; Alan R. Battersby

doi:10.1039/p19940001893

Synthesis and X-Ray structure analysis of 13,17-bis(2-methoxycarbonylethyl) -12,18-bis(methoxycarbonylmethyl)-2,2,8,8,20-pentamethylisobacteriochlorin

Colin L. Gibson
, Michael J. Doyle
, Paul R. Raithby
, Alan R. Battersby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

An improved synthesis is developed for the crystalline isobacteriochlorin 5 which carries a 20-methyl group. X-Ray analysis shows that the molecule 5 is substantially puckered in contrast to a close relative lacking the 20-methyl group which is planar.

Original language	English
Pages (from-to)	1893-1895
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	14
DOIs	https://doi.org/10.1039/p19940001893
Publication status	Published - 1 Jan 1994

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1039/p19940001893

Cite this

Synthesis and X-Ray structure analysis of 13,17-bis(2-methoxycarbonylethyl) -12,18-bis(methoxycarbonylmethyl)-2,2,8,8,20-pentamethylisobacteriochlorin. / Gibson, Colin L.; Doyle, Michael J.; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Perkin Transactions 1, No. 14, 01.01.1994, p. 1893-1895.

Research output: Contribution to journal › Article › peer-review

@article{13d99a625b06480094188042f2b054ab,

title = "Synthesis and X-Ray structure analysis of 13,17-bis(2-methoxycarbonylethyl) -12,18-bis(methoxycarbonylmethyl)-2,2,8,8,20-pentamethylisobacteriochlorin",

abstract = "An improved synthesis is developed for the crystalline isobacteriochlorin 5 which carries a 20-methyl group. X-Ray analysis shows that the molecule 5 is substantially puckered in contrast to a close relative lacking the 20-methyl group which is planar.",

author = "Gibson, \{Colin L.\} and Doyle, \{Michael J.\} and Raithby, \{Paul R.\} and Battersby, \{Alan R.\}",

year = "1994",

month = jan,

day = "1",

doi = "10.1039/p19940001893",

language = "English",

pages = "1893--1895",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "1472-7781",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - Synthesis and X-Ray structure analysis of 13,17-bis(2-methoxycarbonylethyl) -12,18-bis(methoxycarbonylmethyl)-2,2,8,8,20-pentamethylisobacteriochlorin

AU - Gibson, Colin L.

AU - Doyle, Michael J.

AU - Raithby, Paul R.

AU - Battersby, Alan R.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - An improved synthesis is developed for the crystalline isobacteriochlorin 5 which carries a 20-methyl group. X-Ray analysis shows that the molecule 5 is substantially puckered in contrast to a close relative lacking the 20-methyl group which is planar.

AB - An improved synthesis is developed for the crystalline isobacteriochlorin 5 which carries a 20-methyl group. X-Ray analysis shows that the molecule 5 is substantially puckered in contrast to a close relative lacking the 20-methyl group which is planar.

UR - https://www.scopus.com/pages/publications/0011137588

U2 - 10.1039/p19940001893

DO - 10.1039/p19940001893

M3 - Article

AN - SCOPUS:0011137588

SN - 1472-7781

SP - 1893

EP - 1895

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 14

ER -

Synthesis and X-Ray structure analysis of 13,17-bis(2-methoxycarbonylethyl) -12,18-bis(methoxycarbonylmethyl)-2,2,8,8,20-pentamethylisobacteriochlorin

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this