Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine

H. G. Ang; W. L. Kwik; W. K. Leong; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1016/0022-328X(90)85483-F

Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os₃(μ-H)(CO)₁₀(μ-P(C₆F₅)H)]: cleavage of a PC bond of a secondary phosphine

H. G. Ang
, W. L. Kwik
, W. K. Leong
, Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby

National University of Singapore
University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the anion [Os₃H(CO)₁₁]^- with bis(pentafluorophenyl)phosphine, (C₆F₅)₂PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os₃(μ-H)(CO)₁₀(μ-P(C₆F₆)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C₆F₅)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle.

Original language	English
Pages (from-to)	C43-C46
Journal	Journal of Organometallic Chemistry
Volume	396
Issue number	2-3
DOIs	https://doi.org/10.1016/0022-328X(90)85483-F
Publication status	Published - 16 Oct 1990

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(90)85483-F

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Ang, H. G., Kwik, W. L., Leong, W. K., Johnson, B. F. G., Lewis, J., & Raithby, P. R. (1990). Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os₃(μ-H)(CO)₁₀(μ-P(C₆F₅)H)]: cleavage of a PC bond of a secondary phosphine. Journal of Organometallic Chemistry, 396(2-3), C43-C46. https://doi.org/10.1016/0022-328X(90)85483-F

Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os₃(μ-H)(CO)₁₀(μ-P(C₆F₅)H)]: cleavage of a PC bond of a secondary phosphine. / Ang, H. G.; Kwik, W. L.; Leong, W. K. et al.
In: Journal of Organometallic Chemistry, Vol. 396, No. 2-3, 16.10.1990, p. C43-C46.

Research output: Contribution to journal › Article › peer-review

@article{987f6b735e8941909e581e1b82338184,

title = "Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine",

abstract = "The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) {\AA}) of the isosceles osmium triangle.",

author = "Ang, \{H. G.\} and Kwik, \{W. L.\} and Leong, \{W. K.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\}",

year = "1990",

month = oct,

day = "16",

doi = "10.1016/0022-328X(90)85483-F",

language = "English",

volume = "396",

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TY - JOUR

T1 - Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]

T2 - cleavage of a PC bond of a secondary phosphine

AU - Ang, H. G.

AU - Kwik, W. L.

AU - Leong, W. K.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1990/10/16

Y1 - 1990/10/16

N2 - The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle.

AB - The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle.

UR - https://www.scopus.com/pages/publications/0038140432

U2 - 10.1016/0022-328X(90)85483-F

DO - 10.1016/0022-328X(90)85483-F

M3 - Article

AN - SCOPUS:0038140432

SN - 0022-328X

VL - 396

SP - C43-C46

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2-3

ER -

Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os₃(μ-H)(CO)₁₀(μ-P(C₆F₅)H)]: cleavage of a PC bond of a secondary phosphine

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