Synthesis and X-ray crystal structure of the cluster [Os6(CO)17(P(OMe)3)4], an example of a hexa-metal planar complex

Robert J. Goudsmit; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Kenton H. Whitmire

doi:10.1039/C39820000640

Synthesis and X-ray crystal structure of the cluster [Os₆(CO)₁₇(P(OMe)₃)₄], an example of a hexa-metal planar complex

Robert J. Goudsmit, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Kenton H. Whitmire

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster [Os₆(CO)₁₇(P(OMe)₃)₄] has been obtained by the reaction of [Os₆(CO)₂₀] with P(OMe)₃; the six Os atoms are approximately coplanar with the central Os₃ triangle having each edge bridged by an Os atom.

Original language	English
Pages (from-to)	640-642
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39820000640
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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title = "Synthesis and X-ray crystal structure of the cluster [Os6(CO)17(P(OMe)3)4], an example of a hexa-metal planar complex",

abstract = "The cluster [Os6(CO)17(P(OMe)3)4] has been obtained by the reaction of [Os6(CO)20] with P(OMe)3; the six Os atoms are approximately coplanar with the central Os3 triangle having each edge bridged by an Os atom.",

author = "Goudsmit, \{Robert J.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Whitmire, \{Kenton H.\}",

year = "1982",

doi = "10.1039/C39820000640",

language = "English",

pages = "640--642",

journal = "Journal of the Chemical Society - Series Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Synthesis and X-ray crystal structure of the cluster [Os6(CO)17(P(OMe)3)4], an example of a hexa-metal planar complex

AU - Goudsmit, Robert J.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Whitmire, Kenton H.

PY - 1982

Y1 - 1982

N2 - The cluster [Os6(CO)17(P(OMe)3)4] has been obtained by the reaction of [Os6(CO)20] with P(OMe)3; the six Os atoms are approximately coplanar with the central Os3 triangle having each edge bridged by an Os atom.

AB - The cluster [Os6(CO)17(P(OMe)3)4] has been obtained by the reaction of [Os6(CO)20] with P(OMe)3; the six Os atoms are approximately coplanar with the central Os3 triangle having each edge bridged by an Os atom.

UR - https://www.scopus.com/pages/publications/37049110914

U2 - 10.1039/C39820000640

DO - 10.1039/C39820000640

M3 - Article

AN - SCOPUS:37049110914

SN - 0022-4936

SP - 640

EP - 642

JO - Journal of the Chemical Society - Series Chemical Communications

JF - Journal of the Chemical Society - Series Chemical Communications

IS - 11

ER -

Synthesis and X-ray crystal structure of the cluster [Os₆(CO)₁₇(P(OMe)₃)₄], an example of a hexa-metal planar complex

Abstract

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