Synthesis and x-ray crystal structure of 2,2′,2″-iminotris(acetamidoxime) copper(II) sulphate monohydrate, [CuN(CH2CNH2: NOH)3(SO4)]·H2O

George A. Pearse; Paul R. Raithby; Maria M.J. Maughan

doi:10.1016/S0277-5387(00)84731-2

Synthesis and x-ray crystal structure of 2,2′,2″-iminotris(acetamidoxime) copper(II) sulphate monohydrate, [CuN(CH₂CNH₂: NOH)₃(SO₄)]·H₂O

George A. Pearse, Paul R. Raithby, Maria M.J. Maughan

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of copper(II) sulphate pentahydrate with 2,2′,2″-iminotris (acetamidoxime) yields green needles of the formula [Cu(C₆H₁₅N₇O₃)(SO₄)]·H₂O for which the X-ray structure determination shows the five coordinate nature of the central Cu^II atom which is bonded to the imine and three oxime nitrogen atoms plus a sulphate molecule to give a slightly distorted trigonal bipyramidal chelate. A solvent water molecule which hydrogen bonds to a sulphate oxygen was located in the crystal lattice.

Original language	English
Pages (from-to)	553-558
Number of pages	6
Journal	Polyhedron
Volume	13
Issue number	4
DOIs	https://doi.org/10.1016/S0277-5387(00)84731-2
Publication status	Published - 31 Dec 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis and x-ray crystal structure of 2,2′,2″-iminotris(acetamidoxime) copper(II) sulphate monohydrate, [CuN(CH2CNH2: NOH)3(SO4)]·H2O",

abstract = "The reaction of copper(II) sulphate pentahydrate with 2,2′,2″-iminotris (acetamidoxime) yields green needles of the formula [Cu(C6H15N7O3)(SO4)]·H2O for which the X-ray structure determination shows the five coordinate nature of the central CuII atom which is bonded to the imine and three oxime nitrogen atoms plus a sulphate molecule to give a slightly distorted trigonal bipyramidal chelate. A solvent water molecule which hydrogen bonds to a sulphate oxygen was located in the crystal lattice.",

author = "Pearse, \{George A.\} and Raithby, \{Paul R.\} and Maughan, \{Maria M.J.\}",

year = "1994",

month = dec,

day = "31",

doi = "10.1016/S0277-5387(00)84731-2",

language = "English",

volume = "13",

pages = "553--558",

journal = "Polyhedron",

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T1 - Synthesis and x-ray crystal structure of 2,2′,2″-iminotris(acetamidoxime) copper(II) sulphate monohydrate, [CuN(CH2CNH2: NOH)3(SO4)]·H2O

AU - Pearse, George A.

AU - Raithby, Paul R.

AU - Maughan, Maria M.J.

PY - 1994/12/31

Y1 - 1994/12/31

N2 - The reaction of copper(II) sulphate pentahydrate with 2,2′,2″-iminotris (acetamidoxime) yields green needles of the formula [Cu(C6H15N7O3)(SO4)]·H2O for which the X-ray structure determination shows the five coordinate nature of the central CuII atom which is bonded to the imine and three oxime nitrogen atoms plus a sulphate molecule to give a slightly distorted trigonal bipyramidal chelate. A solvent water molecule which hydrogen bonds to a sulphate oxygen was located in the crystal lattice.

AB - The reaction of copper(II) sulphate pentahydrate with 2,2′,2″-iminotris (acetamidoxime) yields green needles of the formula [Cu(C6H15N7O3)(SO4)]·H2O for which the X-ray structure determination shows the five coordinate nature of the central CuII atom which is bonded to the imine and three oxime nitrogen atoms plus a sulphate molecule to give a slightly distorted trigonal bipyramidal chelate. A solvent water molecule which hydrogen bonds to a sulphate oxygen was located in the crystal lattice.

UR - https://www.scopus.com/pages/publications/0003554637

U2 - 10.1016/S0277-5387(00)84731-2

DO - 10.1016/S0277-5387(00)84731-2

M3 - Article

AN - SCOPUS:0003554637

SN - 0277-5387

VL - 13

SP - 553

EP - 558

JO - Polyhedron

JF - Polyhedron

IS - 4

ER -

Synthesis and x-ray crystal structure of 2,2′,2″-iminotris(acetamidoxime) copper(II) sulphate monohydrate, [CuN(CH₂CNH₂: NOH)₃(SO₄)]·H₂O

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