Synthesis and X-ray crystal structure analysis of a novel μ4-oxo undeca-osmium carbonyl cluster [Os114-O)3(CO)30]

Scott L. Ingham, Jack Lewis, Paul R. Raithby

Research output: Contribution to journalArticlepeer-review

Abstract

The first example of an osmium cluster containing μ4-oxo groups, [Os114-O)(CO)30] 1, has been obtained from the vacuum pyrolysis of [Os3H(CO)10(μ-OH) ], and has been shown by X-ray crystallography to contain a tri-edge bridged, bicapped trigonal prismatic metal core.

Original languageEnglish
Pages (from-to)166-167
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
Publication statusPublished - 1993

ASJC Scopus subject areas

  • Molecular Medicine

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