Synthesis and x-ray crystal and molecular structure of the mixed-metal cluster anion [Os6Au(CO)20H2]-

Brian F.G. Johnson; David A. Kaner; Jack Lewis; Paul R. Raithby

doi:10.1039/c39810000753

Synthesis and x-ray crystal and molecular structure of the mixed-metal cluster anion [Os₆Au(CO)₂₀H₂]^-

Brian F.G. Johnson, David A. Kaner, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The unsaturated mixed-metal cluster anion [Os₆Au(CO) ₂₀H₂]^- has been prepared as its [N(PPh ₃)₂]⁺ salt by the reaction of [Os ₃Au(CO)₁₀(PR₃)H] (R = Ph, Et) with [N(PPh ₃)₂]Cl; its X-ray crystal structure shows that the Au ^I atom links two 'Os₃(CO)₁₀H' units via co-ordination to two short Os-Os bonds.

Original language	English
Pages (from-to)	753-755
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/c39810000753
Publication status	Published - 31 Dec 1981

ASJC Scopus subject areas

Molecular Medicine

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title = "Synthesis and x-ray crystal and molecular structure of the mixed-metal cluster anion [Os6Au(CO)20H2]-",

abstract = "The unsaturated mixed-metal cluster anion [Os6Au(CO) 20H2]- has been prepared as its [N(PPh 3)2]+ salt by the reaction of [Os 3Au(CO)10(PR3)H] (R = Ph, Et) with [N(PPh 3)2]Cl; its X-ray crystal structure shows that the Au I atom links two 'Os3(CO)10H' units via co-ordination to two short Os-Os bonds.",

author = "Johnson, \{Brian F.G.\} and Kaner, \{David A.\} and Jack Lewis and Raithby, \{Paul R.\}",

year = "1981",

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doi = "10.1039/c39810000753",

language = "English",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Synthesis and x-ray crystal and molecular structure of the mixed-metal cluster anion [Os6Au(CO)20H2]-

AU - Johnson, Brian F.G.

AU - Kaner, David A.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1981/12/31

Y1 - 1981/12/31

N2 - The unsaturated mixed-metal cluster anion [Os6Au(CO) 20H2]- has been prepared as its [N(PPh 3)2]+ salt by the reaction of [Os 3Au(CO)10(PR3)H] (R = Ph, Et) with [N(PPh 3)2]Cl; its X-ray crystal structure shows that the Au I atom links two 'Os3(CO)10H' units via co-ordination to two short Os-Os bonds.

AB - The unsaturated mixed-metal cluster anion [Os6Au(CO) 20H2]- has been prepared as its [N(PPh 3)2]+ salt by the reaction of [Os 3Au(CO)10(PR3)H] (R = Ph, Et) with [N(PPh 3)2]Cl; its X-ray crystal structure shows that the Au I atom links two 'Os3(CO)10H' units via co-ordination to two short Os-Os bonds.

UR - https://www.scopus.com/pages/publications/37049106547

U2 - 10.1039/c39810000753

DO - 10.1039/c39810000753

M3 - Article

AN - SCOPUS:37049106547

SN - 0022-4936

SP - 753

EP - 755

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 15

ER -

Synthesis and x-ray crystal and molecular structure of the mixed-metal cluster anion [Os₆Au(CO)₂₀H₂]^-

Abstract

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