Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

G. Kociok-Köhn; M.F. Mahon; K.C. Molloy; A.L. Sudlow

doi:10.1515/mgmc-2013-0051

Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

G. Kociok-Köhn
, M.F. Mahon
, K.C. Molloy
, A.L. Sudlow

Research output: Contribution to journal › Article › peer-review

14 Citations (SciVal)

487 Downloads (Pure)

Abstract

The novel bimetallic adducts [(Ph₃P)₂CuCl]₂.ZnCl₂ (1), {[(Me₃P)CuCl]_2.ZnCI₂l}n (2), [(Me₃P)Cu]⁺[(Me₃P)₂Cu(Cl₂)ZnCl₂]- (3), (Ph₃P)₂CuC.ISnCl₂ (4), (Me₃P3)₃CuSnCl₃ (5), [(Ph₃P)₂CuCl.SbCI₃]₂ (6) and (Ph₃P)₃CuCl.SbCl₃ (7) have been synthesized from combinations of RP₃, CuCl and one of ZnCl₂, SnCl₂ or SbCl₃, and their structures were determined. [(Me₃P)₂Cu]⁺[HPMe₃]₂⁺[Sb₂Cl_g]^3-(8) and [(Me₃P)₄Cu]⁺[(Me₃P)₂Sb₂Cl_z]^- (9) have been isolated as minor by-products from the reaction of Me₃P, CuCl and SbCl₃, and their structures were also determined.

Original language	English
Pages (from-to)	11-24
Number of pages	14
Journal	Main Group Metal Chemistry
Volume	37
Issue number	1-2
Early online date	10 Mar 2014
DOIs	https://doi.org/10.1515/mgmc-2013-0051
Publication status	Published - Mar 2014

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10.1515/mgmc-2013-0051

synthesis and structures of Cu-Cl-M adducts
This is the published version of an article published by De Gruyter and available via: http://dx.doi.org/10.1515/mgmc-2013-0051
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@article{1523fbafb5484023826d8af1a30ec25f,

title = "Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)",

abstract = "The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), \{[(Me3P)CuCl]2.ZnCI2l\}n (2), [(Me3P)Cu]+[(Me3P)2Cu(Cl2)ZnCl2]- (3), (Ph3P)2CuC.ISnCl2 (4), (Me3P3)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCI3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of RP3, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Clg]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Clz]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.",

author = "G. Kociok-K{\"o}hn and M.F. Mahon and K.C. Molloy and A.L. Sudlow",

year = "2014",

month = mar,

doi = "10.1515/mgmc-2013-0051",

language = "English",

volume = "37",

pages = "11--24",

journal = "Main Group Metal Chemistry",

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TY - JOUR

T1 - Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

AU - Kociok-Köhn, G.

AU - Mahon, M.F.

AU - Molloy, K.C.

AU - Sudlow, A.L.

PY - 2014/3

Y1 - 2014/3

N2 - The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2), [(Me3P)Cu]+[(Me3P)2Cu(Cl2)ZnCl2]- (3), (Ph3P)2CuC.ISnCl2 (4), (Me3P3)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCI3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of RP3, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Clg]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Clz]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.

AB - The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2), [(Me3P)Cu]+[(Me3P)2Cu(Cl2)ZnCl2]- (3), (Ph3P)2CuC.ISnCl2 (4), (Me3P3)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCI3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of RP3, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Clg]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Clz]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.

UR - https://www.scopus.com/pages/publications/84902474554

UR - http://dx.doi.org/10.1515/mgmc-2013-0051

U2 - 10.1515/mgmc-2013-0051

DO - 10.1515/mgmc-2013-0051

M3 - Article

AN - SCOPUS:84902474554

SN - 0792-1241

VL - 37

SP - 11

EP - 24

JO - Main Group Metal Chemistry

JF - Main Group Metal Chemistry

IS - 1-2

ER -

Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

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