Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)

G. Kociok-Köhn, M.F. Mahon, K.C. Molloy, A.L. Sudlow

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Abstract

The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2), [(Me3P)Cu]+[(Me3P)2Cu(Cl2)ZnCl2]- (3), (Ph3P)2CuC.ISnCl2 (4), (Me3P3)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCI3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of RP3, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Clg]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Clz]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.

Original languageEnglish
Pages (from-to)11-24
Number of pages14
JournalMain Group Metal Chemistry
Volume37
Issue number1-2
Early online date10 Mar 2014
DOIs
Publication statusPublished - Mar 2014

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