TY - JOUR
T1 - Synthesis and structures of Cu-Cl-M adducts (M = Zn, Sn, Sb)
AU - Kociok-Köhn, G.
AU - Mahon, M.F.
AU - Molloy, K.C.
AU - Sudlow, A.L.
PY - 2014/3
Y1 - 2014/3
N2 - The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2), [(Me3P)Cu]+[(Me3P)2Cu(Cl2)ZnCl2]- (3), (Ph3P)2CuC.ISnCl2 (4), (Me3P3)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCI3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of RP3, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Clg]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Clz]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.
AB - The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCI2l}n (2), [(Me3P)Cu]+[(Me3P)2Cu(Cl2)ZnCl2]- (3), (Ph3P)2CuC.ISnCl2 (4), (Me3P3)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCI3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of RP3, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Clg]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Clz]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.
UR - http://www.scopus.com/inward/record.url?scp=84902474554&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1515/mgmc-2013-0051
U2 - 10.1515/mgmc-2013-0051
DO - 10.1515/mgmc-2013-0051
M3 - Article
AN - SCOPUS:84902474554
SN - 0792-1241
VL - 37
SP - 11
EP - 24
JO - Main Group Metal Chemistry
JF - Main Group Metal Chemistry
IS - 1-2
ER -