Synthesis and structure of the mixed anion sandwich complex {[(C 5H5)9Pb4]-[(C 5H5)5Pb2]-[Li(12-crown-4) 2]+2}

Melinda J. Duer, Nicola A. Page, Michael A. Paver, Paul R. Raithby, Moira Ann Rennie, Christopher A. Russell, Clare Stourton, Alexander Steiner, Dominic S. Wright

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Abstract

The title compound, {[(C5H5)9Pb 4]-[(C5H5)5Pb 2]-[Li(12-crown-4)2]+2} 1, is synthesised by the reaction of [(C5H5) 2Pb] and [(C5H5)Li] and 12-crown-4 (3:1:2 equiv.), and is shown by X-ray diffraction to contain both a quintuple-decker and a triple-decker sandwich anion; in contrast, the corresponding reaction with [(C5H5)2Sn] (which possesses no such polymeric lattice of its own) in place of [(C5H5) 2Pb] yields the simple 'paddlewheel' molecule {[(C5H5)3Sn]-[Li(12-crown-4) 2]+}2.

Original languageEnglish
Pages (from-to)1141-1142
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume1995
Issue number11
DOIs
Publication statusPublished - 31 Dec 1995

ASJC Scopus subject areas

  • Molecular Medicine

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