Abstract
The amine PhCH2CH2NH2 undergoes dimetallation by [Ph3Sb(NMe2)2] (1) under mild conditions to give the first structurally authenticated example of an organo-Sb(V) imido complex, [Ph3Sb(μ-NCH2CH2Ph)]2 (2).
Original language | English |
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Pages (from-to) | C29-C31 |
Journal | Journal of Organometallic Chemistry |
Volume | 503 |
Issue number | 1 |
DOIs | |
Publication status | Published - 1 Nov 1995 |
Funding
We gratefully acknowledge support by the EPSRC (A.J.E., M.A.P., P.R.R., C.A.R., D.S.W.), the Associated Octel Co., Ltd., Ellesmere Port, U.K. (M.A.P., D.S.W.), the Royal Society (P.R.R., D.S.W.), the Nuffield Foundation (D.S.W.), and the Cambridge Crystallography Data Centre CM.-A.R.).
Funders | Funder number |
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Associated Octel Co. Ltd. | |
Engineering and Physical Sciences Research Council | |
The Nuffield Foundation | |
Royal Society |
Keywords
- Antimony
- Crystal structure
- Dimer
- Group 15
- Imido
- Metallation
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry