Synthesis and Structure of the Bis(imido)gold Complex [Au51(NtBu)2(PPh3)4] + Cl-·2 C6H5CH3; a Higher Homologue of the Organotris-(triphenylphosphaneaurio)ammonium Ions

Robert E. Allan, Michael A. Beswick, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

Research output: Contribution to journalArticlepeer-review

Abstract

A “bowtie-shaped” Au5 moiety (structure shown on the right, PPh3 ligands on the terminal Au centers have been omitted) is the characteristic structural feature of the title complex. This is formed in high yield by the reaction of [AuCl(PPh3)] with [tBuNHLi] (1:1 equiv) in toluene. The cation can be regarded as the next homologue of cations of the type [(AuPPh3)3NR]+ and is the largest structurally characterized imidogold(I) species to date.

Original languageEnglish
Pages (from-to)208-209
Number of pages2
JournalAngewandte Chemie (International Edition in English)
Volume35
Issue number2
DOIs
Publication statusPublished - 2 Feb 1996

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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