Synthesis and structure of sulfide aluminate sodalites

Matthew E. Brenchley, Mark T. Weller

Research output: Contribution to journalArticle

Abstract

The compounds Sr[AlO]S and Ca[AlO]S have been prepared by reduction of the corresponding sulfate materials, M [AlO]·(SO) via an intra-cage reaction. The materials crystallise with the simple body-centred cubic sodalite structure. Profile refinement of powder X-ray data has been undertaken showing a tetrahedral coordination around sulfur and a distorted sevemold coordination for the alkaline-earth metals.
Original languageEnglish
Pages (from-to)1003-1005
JournalJournal of Materials Chemistry
Volume2
Issue number10
DOIs
Publication statusPublished - 1992

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