Synthesis and structure of [Sb2Li2{N(C 6H11)}4]2; a cage complex containing a core of two interlocked 'broken' cubes

Russell A. Alton; Donald Barr; Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Moira Ann Rennie; Christopher A. Russell; Dominic S. Wright

doi:10.1039/C39940001481

Synthesis and structure of [Sb₂Li₂{N(C ₆H₁₁)}₄]₂; a cage complex containing a core of two interlocked 'broken' cubes

Russell A. Alton
, Donald Barr
, Andrew J. Edwards
, Michael A. Paver
, Paul R. Raithby
, Moira Ann Rennie
, Christopher A. Russell
, Dominic S. Wright

University of Cambridge
Associated Octel Co. Ltd.

Research output: Contribution to journal › Article › peer-review

Abstract

The imido cage complex [Sb₂Li₂{N(C₆H ₁₁)}₄]₂, synthesised by the condensation reaction of dimeric [Sb(NMe₂){μ-N(C₆H ₁₁)}]₂ with [LiNH(C₆H₁₁)] _n (1 : 1 monomer equiv.) consists of an Sb₄Li ₄N₈ polyhedral core which can be viewed as being constructed from two interlocked 'broken' cubes.

Original language	English
Pages (from-to)	1481-1482
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39940001481
Publication status	Published - 1994

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39940001481

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title = "Synthesis and structure of [Sb2Li2\{N(C 6H11)\}4]2; a cage complex containing a core of two interlocked 'broken' cubes",

abstract = "The imido cage complex [Sb2Li2\{N(C6H 11)\}4]2, synthesised by the condensation reaction of dimeric [Sb(NMe2)\{μ-N(C6H 11)\}]2 with [LiNH(C6H11)] n (1 : 1 monomer equiv.) consists of an Sb4Li 4N8 polyhedral core which can be viewed as being constructed from two interlocked 'broken' cubes.",

author = "Alton, \{Russell A.\} and Donald Barr and Edwards, \{Andrew J.\} and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Rennie, \{Moira Ann\} and Russell, \{Christopher A.\} and Wright, \{Dominic S.\}",

year = "1994",

doi = "10.1039/C39940001481",

language = "English",

pages = "1481--1482",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "12",

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TY - JOUR

T1 - Synthesis and structure of [Sb2Li2{N(C 6H11)}4]2; a cage complex containing a core of two interlocked 'broken' cubes

AU - Alton, Russell A.

AU - Barr, Donald

AU - Edwards, Andrew J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Rennie, Moira Ann

AU - Russell, Christopher A.

AU - Wright, Dominic S.

PY - 1994

Y1 - 1994

N2 - The imido cage complex [Sb2Li2{N(C6H 11)}4]2, synthesised by the condensation reaction of dimeric [Sb(NMe2){μ-N(C6H 11)}]2 with [LiNH(C6H11)] n (1 : 1 monomer equiv.) consists of an Sb4Li 4N8 polyhedral core which can be viewed as being constructed from two interlocked 'broken' cubes.

AB - The imido cage complex [Sb2Li2{N(C6H 11)}4]2, synthesised by the condensation reaction of dimeric [Sb(NMe2){μ-N(C6H 11)}]2 with [LiNH(C6H11)] n (1 : 1 monomer equiv.) consists of an Sb4Li 4N8 polyhedral core which can be viewed as being constructed from two interlocked 'broken' cubes.

UR - https://www.scopus.com/pages/publications/37049085039

U2 - 10.1039/C39940001481

DO - 10.1039/C39940001481

M3 - Article

AN - SCOPUS:37049085039

SN - 0022-4936

SP - 1481

EP - 1482

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 12

ER -

Synthesis and structure of [Sb₂Li₂{N(C ₆H₁₁)}₄]₂; a cage complex containing a core of two interlocked 'broken' cubes

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