Synthesis and structure of [Pb(2-Py)3Li·THF], containing a low-valent group 14 tris(pyridyl) ligand (2-py = 2-pyridyl)

Michael A. Beswick; Maxwell K. Davies; Paul R. Raithby; Alexander Steiner; Dominic S. Wright

doi:10.1021/om9609123

Synthesis and structure of [Pb(2-Py)₃Li·THF], containing a low-valent group 14 tris(pyridyl) ligand (2-py = 2-pyridyl)

Michael A. Beswick, Maxwell K. Davies, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

41 Citations (SciVal)

Abstract

The reaction of [2-PyLi] with [Cp₂Pb] produces [Pb(2-Py)₃Li·THF] (1), containing the first example of a low oxidation state group 14 tris(pyridyl) ligand. The solid-state structure of 1 is that of a cage resulting from the symmetrical complexation of the Li₊ cation by all the pyridyl-N centers of the [Pb(2-Py)₃]^- anion.

Original language	English
Pages (from-to)	1109-1110
Number of pages	2
Journal	Organometallics
Volume	16
Issue number	6
DOIs	https://doi.org/10.1021/om9609123
Publication status	Published - 18 Mar 1997

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis and structure of [Pb(2-Py)3Li·THF], containing a low-valent group 14 tris(pyridyl) ligand (2-py = 2-pyridyl)",

abstract = "The reaction of [2-PyLi] with [Cp2Pb] produces [Pb(2-Py)3Li·THF] (1), containing the first example of a low oxidation state group 14 tris(pyridyl) ligand. The solid-state structure of 1 is that of a cage resulting from the symmetrical complexation of the Li+ cation by all the pyridyl-N centers of the [Pb(2-Py)3]- anion.",

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AU - Beswick, Michael A.

AU - Davies, Maxwell K.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1997/3/18

Y1 - 1997/3/18

N2 - The reaction of [2-PyLi] with [Cp2Pb] produces [Pb(2-Py)3Li·THF] (1), containing the first example of a low oxidation state group 14 tris(pyridyl) ligand. The solid-state structure of 1 is that of a cage resulting from the symmetrical complexation of the Li+ cation by all the pyridyl-N centers of the [Pb(2-Py)3]- anion.

AB - The reaction of [2-PyLi] with [Cp2Pb] produces [Pb(2-Py)3Li·THF] (1), containing the first example of a low oxidation state group 14 tris(pyridyl) ligand. The solid-state structure of 1 is that of a cage resulting from the symmetrical complexation of the Li+ cation by all the pyridyl-N centers of the [Pb(2-Py)3]- anion.

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U2 - 10.1021/om9609123

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ER -

Synthesis and structure of [Pb(2-Py)₃Li·THF], containing a low-valent group 14 tris(pyridyl) ligand (2-py = 2-pyridyl)

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