Synthesis and structure of [{(Me3Si)2N}2Cd{(PhN)3C}Li 2·3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments

Philip J. Bailey; Lindsey A. Mitchell; Paul R. Raithby; Moira Ann Rennie; Kerry Verhorevoort; Dominic S. Wright

doi:10.1039/CC9960001351

Synthesis and structure of [{(Me₃Si)₂N}₂Cd{(PhN)₃C}Li ₂·3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments

Philip J. Bailey
, Lindsey A. Mitchell
, Paul R. Raithby
, Moira Ann Rennie
, Kerry Verhorevoort
, Dominic S. Wright

Edinburgh Napier University
University of Cambridge

Research output: Contribution to journal › Article › peer-review

23 Citations (SciVal)

Abstract

Dilithio-1,2,3-triphenylguanidide, [{(PhN)₃C}Li₂], reacts with [Cd{N(SiMe₃)₂}] to give [{(Me₃Si)₂N}₂Cd{(PhN)₃}Li ₂·3thf] 1; a novel co-complex containing three different metal coordination environments.

Original language	English
Pages (from-to)	1351-1352
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/CC9960001351
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/CC9960001351

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@article{3c9292a31b834b6a8784342d4b41dbdb,

title = "Synthesis and structure of [\{(Me3Si)2N\}2Cd\{(PhN)3C\}Li 2·3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments",

abstract = "Dilithio-1,2,3-triphenylguanidide, [\{(PhN)3C\}Li2], reacts with [Cd\{N(SiMe3)2\}] to give [\{(Me3Si)2N\}2Cd\{(PhN)3\}Li 2·3thf] 1; a novel co-complex containing three different metal coordination environments.",

author = "Bailey, \{Philip J.\} and Mitchell, \{Lindsey A.\} and Raithby, \{Paul R.\} and Rennie, \{Moira Ann\} and Kerry Verhorevoort and Wright, \{Dominic S.\}",

year = "1996",

month = jan,

day = "1",

doi = "10.1039/CC9960001351",

language = "English",

pages = "1351--1352",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

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TY - JOUR

T1 - Synthesis and structure of [{(Me3Si)2N}2Cd{(PhN)3C}Li 2·3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments

AU - Bailey, Philip J.

AU - Mitchell, Lindsey A.

AU - Raithby, Paul R.

AU - Rennie, Moira Ann

AU - Verhorevoort, Kerry

AU - Wright, Dominic S.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Dilithio-1,2,3-triphenylguanidide, [{(PhN)3C}Li2], reacts with [Cd{N(SiMe3)2}] to give [{(Me3Si)2N}2Cd{(PhN)3}Li 2·3thf] 1; a novel co-complex containing three different metal coordination environments.

AB - Dilithio-1,2,3-triphenylguanidide, [{(PhN)3C}Li2], reacts with [Cd{N(SiMe3)2}] to give [{(Me3Si)2N}2Cd{(PhN)3}Li 2·3thf] 1; a novel co-complex containing three different metal coordination environments.

UR - https://www.scopus.com/pages/publications/0002427623

U2 - 10.1039/CC9960001351

DO - 10.1039/CC9960001351

M3 - Article

AN - SCOPUS:0002427623

SN - 1359-7345

SP - 1351

EP - 1352

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Synthesis and structure of [{(Me₃Si)₂N}₂Cd{(PhN)₃C}Li ₂·3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments

Abstract

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