Synthesis and structure of [{ButP2H}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]

Michael A. Beswick; Alexander D. Hopkins; Lesley C. Kerr; Marta E.G. Mosquera; Julie S. Palmer; Paul R. Raithby; Alexander Rothenberger; D. Stalke; Alexander Steiner; Andrew E.H. Wheatley; Dominic S. Wright

doi:10.1039/a803834a

Synthesis and structure of [{Bu^tP₂H}K·pmdeta]₂, containing an organo diphosphido ligand [pmdeta = (Me₂NCH₂CH₂)₂NMe]

Michael A. Beswick, Alexander D. Hopkins, Lesley C. Kerr, Marta E.G. Mosquera, Julie S. Palmer, Paul R. Raithby, Alexander Rothenberger, D. Stalke, Alexander Steiner, Andrew E.H. Wheatley, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

Reduction of [Bu^tP]₄ with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(Bu^tP)₂H}K·pmdeta]₂, a unique complex containing a [Bu^tP(H)PBu^t]^- anion ligand homologous with a phosphido anion (R₂P^-).

Original language	English
Pages (from-to)	1527-1528
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/a803834a
Publication status	Published - 7 Aug 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a803834a

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Beswick, M. A., Hopkins, A. D., Kerr, L. C., Mosquera, M. E. G., Palmer, J. S., Raithby, P. R., Rothenberger, A., Stalke, D., Steiner, A., Wheatley, A. E. H., & Wright, D. S. (1998). Synthesis and structure of [{Bu^tP₂H}K·pmdeta]₂, containing an organo diphosphido ligand [pmdeta = (Me₂NCH₂CH₂)₂NMe]. Chemical Communications, (15), 1527-1528. https://doi.org/10.1039/a803834a

@article{6a623f686b374b64abc9a8e6416eca68,

title = "Synthesis and structure of [\{ButP2H\}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]",

abstract = "Reduction of [ButP]4 with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [\{(ButP)2H\}K·pmdeta]2, a unique complex containing a [ButP(H)PBut]- anion ligand homologous with a phosphido anion (R2P-).",

author = "Beswick, \{Michael A.\} and Hopkins, \{Alexander D.\} and Kerr, \{Lesley C.\} and Mosquera, \{Marta E.G.\} and Palmer, \{Julie S.\} and Raithby, \{Paul R.\} and Alexander Rothenberger and D. Stalke and Alexander Steiner and Wheatley, \{Andrew E.H.\} and Wright, \{Dominic S.\}",

year = "1998",

month = aug,

day = "7",

doi = "10.1039/a803834a",

language = "English",

pages = "1527--1528",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - Synthesis and structure of [{ButP2H}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]

AU - Beswick, Michael A.

AU - Hopkins, Alexander D.

AU - Kerr, Lesley C.

AU - Mosquera, Marta E.G.

AU - Palmer, Julie S.

AU - Raithby, Paul R.

AU - Rothenberger, Alexander

AU - Stalke, D.

AU - Steiner, Alexander

AU - Wheatley, Andrew E.H.

AU - Wright, Dominic S.

PY - 1998/8/7

Y1 - 1998/8/7

N2 - Reduction of [ButP]4 with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(ButP)2H}K·pmdeta]2, a unique complex containing a [ButP(H)PBut]- anion ligand homologous with a phosphido anion (R2P-).

AB - Reduction of [ButP]4 with K metal (1:5 equiv.) followed by the addition of pmdeta and stoichiometric hydrolysis gives [{(ButP)2H}K·pmdeta]2, a unique complex containing a [ButP(H)PBut]- anion ligand homologous with a phosphido anion (R2P-).

UR - https://www.scopus.com/pages/publications/0003089022

U2 - 10.1039/a803834a

DO - 10.1039/a803834a

M3 - Article

AN - SCOPUS:0003089022

SN - 1359-7345

SP - 1527

EP - 1528

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Synthesis and structure of [{Bu^tP₂H}K·pmdeta]₂, containing an organo diphosphido ligand [pmdeta = (Me₂NCH₂CH₂)₂NMe]

Abstract

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