Synthesis and structure of [{As2(NCy)4}2Li4], containing an imido As(III) dianion

Michael A. Beswick, Eilis A. Harron, Alexander D. Hopkins, Paul R. Raithby, Dominic S. Wright

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Reaction of [As(NMe2)3] with CyNH2 (1:1 equivalents), followed by the addition of [CyNHLi] (1 equivalent) gives the heterobimetallic cage complex [{As2(NCy)4}2Li4], the first example of a complex containing an imido As(III) anion; the missing link in a series of Group 15 anions of the type [{E2(NCy)4}]2- (E = Bi, Sb and P).

Original languageEnglish
Pages (from-to)107-108
Number of pages2
JournalJournal of the Chemical Society - Dalton Transactions
Issue number2
DOIs
Publication statusPublished - 21 Jan 1999

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Synthesis and structure of [{As<sub>2</sub>(NCy)<sub>4</sub>}<sub>2</sub>Li<sub>4</sub>], containing an imido As(III) dianion'. Together they form a unique fingerprint.

Cite this