Synthesis and structure of [{As(NtBu)3}2Li6] containing an [As(NtBu)3]3- trianion

Michael A. Beswick; Sara J. Kidd; Michael A. Paver; Paul R. Raithby; Alexander Steiner; Dominic S. Wright

doi:10.1016/S1387-7003(99)00168-9

Synthesis and structure of [{As(N^tBu)₃}₂Li₆] containing an [As(N^tBu)₃]^3- trianion

Michael A. Beswick
, Sara J. Kidd
, Michael A. Paver
, Paul R. Raithby
, Alexander Steiner
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

15 Citations (SciVal)

Abstract

Attempts to prepare the [As(N^tBu)₃]^3- trianion by the reaction of As(NMe₂)₃ with [^tBuNHLi]_n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of ^tBuNH₂ (3 equiv.) the target complex [{As(N^tBu)₃}₂Li₆] (1) is obtained. This is the first example of a complex containing an [As(NR)₃]^3- trianion.

Original language	English
Pages (from-to)	612-614
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	2
Issue number	12
DOIs	https://doi.org/10.1016/S1387-7003(99)00168-9
Publication status	Published - 1 Dec 1999

Funding

We gratefully acknowledge the EPSRC (S.J.K.), the Leverhulme Trust (M.A.B.), the Royal Society (P.R.R., D.S.W.) and Jesus College Cambridge (fellowship for M.A.P.) for financial support. We also thank Dr. J.E. Davies for collecting X-ray data for 1 .

Keywords

Arsenic compound
Crystal structures
Imido compound
Lithium compound
Trianion

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S1387-7003(99)00168-9

Cite this

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title = "Synthesis and structure of [\{As(NtBu)3\}2Li6] containing an [As(NtBu)3]3- trianion",

abstract = "Attempts to prepare the [As(NtBu)3]3- trianion by the reaction of As(NMe2)3 with [tBuNHLi]n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of tBuNH2 (3 equiv.) the target complex [\{As(NtBu)3\}2Li6] (1) is obtained. This is the first example of a complex containing an [As(NR)3]3- trianion.",

keywords = "Arsenic compound, Crystal structures, Imido compound, Lithium compound, Trianion",

author = "Beswick, \{Michael A.\} and Kidd, \{Sara J.\} and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Alexander Steiner and Wright, \{Dominic S.\}",

year = "1999",

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doi = "10.1016/S1387-7003(99)00168-9",

language = "English",

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journal = "Inorganic Chemistry Communications",

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T1 - Synthesis and structure of [{As(NtBu)3}2Li6] containing an [As(NtBu)3]3- trianion

AU - Beswick, Michael A.

AU - Kidd, Sara J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Attempts to prepare the [As(NtBu)3]3- trianion by the reaction of As(NMe2)3 with [tBuNHLi]n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of tBuNH2 (3 equiv.) the target complex [{As(NtBu)3}2Li6] (1) is obtained. This is the first example of a complex containing an [As(NR)3]3- trianion.

AB - Attempts to prepare the [As(NtBu)3]3- trianion by the reaction of As(NMe2)3 with [tBuNHLi]n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of tBuNH2 (3 equiv.) the target complex [{As(NtBu)3}2Li6] (1) is obtained. This is the first example of a complex containing an [As(NR)3]3- trianion.

KW - Arsenic compound

KW - Crystal structures

KW - Imido compound

KW - Lithium compound

KW - Trianion

UR - https://www.scopus.com/pages/publications/0033275785

U2 - 10.1016/S1387-7003(99)00168-9

DO - 10.1016/S1387-7003(99)00168-9

M3 - Article

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SN - 1387-7003

VL - 2

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EP - 614

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

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