Synthesis and structure of [{As(NtBu)3}2Li6] containing an [As(NtBu)3]3- trianion

Michael A. Beswick; Sara J. Kidd; Michael A. Paver; Paul R. Raithby; Alexander Steiner; Dominic S. Wright

doi:10.1016/S1387-7003(99)00168-9

Synthesis and structure of [{As(N^tBu)₃}₂Li₆] containing an [As(N^tBu)₃]^3- trianion

Michael A. Beswick, Sara J. Kidd, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

Research output: Contribution to journal › Article

14 Citations (Scopus)

Abstract

Attempts to prepare the [As(N^tBu)₃]^3- trianion by the reaction of As(NMe₂)₃ with [^tBuNHLi]_n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of ^tBuNH₂ (3 equiv.) the target complex [{As(N^tBu)₃}₂Li₆] (1) is obtained. This is the first example of a complex containing an [As(NR)₃]^3- trianion.

Original language	English
Pages (from-to)	612-614
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	2
Issue number	12
DOIs	https://doi.org/10.1016/S1387-7003(99)00168-9
Publication status	Published - 1 Dec 1999

Keywords

Arsenic compound
Crystal structures
Imido compound
Lithium compound
Trianion

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S1387-7003(99)00168-9

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title = "Synthesis and structure of [{As(NtBu)3}2Li6] containing an [As(NtBu)3]3- trianion",

abstract = "Attempts to prepare the [As(NtBu)3]3- trianion by the reaction of As(NMe2)3 with [tBuNHLi]n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of tBuNH2 (3 equiv.) the target complex [{As(NtBu)3}2Li6] (1) is obtained. This is the first example of a complex containing an [As(NR)3]3- trianion.",

keywords = "Arsenic compound, Crystal structures, Imido compound, Lithium compound, Trianion",

author = "Beswick, {Michael A.} and Kidd, {Sara J.} and Paver, {Michael A.} and Raithby, {Paul R.} and Alexander Steiner and Wright, {Dominic S.}",

year = "1999",

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doi = "10.1016/S1387-7003(99)00168-9",

language = "English",

volume = "2",

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T1 - Synthesis and structure of [{As(NtBu)3}2Li6] containing an [As(NtBu)3]3- trianion

AU - Beswick, Michael A.

AU - Kidd, Sara J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Attempts to prepare the [As(NtBu)3]3- trianion by the reaction of As(NMe2)3 with [tBuNHLi]n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of tBuNH2 (3 equiv.) the target complex [{As(NtBu)3}2Li6] (1) is obtained. This is the first example of a complex containing an [As(NR)3]3- trianion.

AB - Attempts to prepare the [As(NtBu)3]3- trianion by the reaction of As(NMe2)3 with [tBuNHLi]n (1:3 monomer equiv.) proved unsuccessful. However, if the reaction is carried out with an excess of tBuNH2 (3 equiv.) the target complex [{As(NtBu)3}2Li6] (1) is obtained. This is the first example of a complex containing an [As(NR)3]3- trianion.

KW - Arsenic compound

KW - Crystal structures

KW - Imido compound

KW - Lithium compound

KW - Trianion

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