Synthesis and Structure of a Sixteen‐Membered (AINCO)4 Ring

Craig M. Bird; Catherine Breheny; Matthew G. Davidson; Andrew J. Edwards; S. Clare Llewellyn; Paul R. Raithby; Ronald Snaith

doi:10.1002/anie.199314831

Synthesis and Structure of a Sixteen‐Membered (AINCO)₄ Ring

Craig M. Bird, Catherine Breheny, Matthew G. Davidson, Andrew J. Edwards, S. Clare Llewellyn, Paul R. Raithby, Ronald Snaith

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The unprecedented ring size in tetramer 1 arises from the alternation of the (Formula Presented.) coordinating units in the sixteen‐membered macrocycle. This alternation spaces out the ring components of the OxO⁻ ligands, and the flat aromatic rings of the ligands align themselves in near‐parallel pairs (shown on the right). Tetramer 1 is prepared from Me₃A1 and OxOH in toluene. (Figure Presented.) (Formula Presented.)

Original language	English
Pages (from-to)	1483-1484
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	32
Issue number	10
DOIs	https://doi.org/10.1002/anie.199314831
Publication status	Published - Oct 1993

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199314831

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title = "Synthesis and Structure of a Sixteen‐Membered (AINCO)4 Ring",

abstract = "The unprecedented ring size in tetramer 1 arises from the alternation of the (Formula Presented.) coordinating units in the sixteen‐membered macrocycle. This alternation spaces out the ring components of the OxO− ligands, and the flat aromatic rings of the ligands align themselves in near‐parallel pairs (shown on the right). Tetramer 1 is prepared from Me3A1 and OxOH in toluene. (Figure Presented.) (Formula Presented.)",

author = "Bird, {Craig M.} and Catherine Breheny and Davidson, {Matthew G.} and Edwards, {Andrew J.} and Llewellyn, {S. Clare} and Raithby, {Paul R.} and Ronald Snaith",

year = "1993",

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AU - Bird, Craig M.

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AU - Davidson, Matthew G.

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AU - Llewellyn, S. Clare

AU - Raithby, Paul R.

AU - Snaith, Ronald

PY - 1993/10

Y1 - 1993/10

N2 - The unprecedented ring size in tetramer 1 arises from the alternation of the (Formula Presented.) coordinating units in the sixteen‐membered macrocycle. This alternation spaces out the ring components of the OxO− ligands, and the flat aromatic rings of the ligands align themselves in near‐parallel pairs (shown on the right). Tetramer 1 is prepared from Me3A1 and OxOH in toluene. (Figure Presented.) (Formula Presented.)

AB - The unprecedented ring size in tetramer 1 arises from the alternation of the (Formula Presented.) coordinating units in the sixteen‐membered macrocycle. This alternation spaces out the ring components of the OxO− ligands, and the flat aromatic rings of the ligands align themselves in near‐parallel pairs (shown on the right). Tetramer 1 is prepared from Me3A1 and OxOH in toluene. (Figure Presented.) (Formula Presented.)

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Synthesis and Structure of a Sixteen‐Membered (AINCO)₄ Ring

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