Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex

S A Cotton, V M A Fisher, P R Raithby, S Schiffers, S J Teat

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)(2)Sc(mu-OMe)(2)Sc(NO3)(2)(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. (C) 2008 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)822-824
Number of pages3
JournalInorganic Chemistry Communications
Volume11
Issue number7
DOIs
Publication statusPublished - 2008

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