Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex

S A Cotton; V M A Fisher; P R Raithby; S Schiffers; S J Teat

doi:10.1016/j.inoche.2008.04.007

Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex

S A Cotton, V M A Fisher, P R Raithby, S Schiffers, S J Teat

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (SciVal)

Abstract

Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)(2)Sc(mu-OMe)(2)Sc(NO3)(2)(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. (C) 2008 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	822-824
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2008.04.007
Publication status	Published - 2008

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ID number: ISI:000257531200031

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10.1016/j.inoche.2008.04.007

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title = "Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex",

abstract = "Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)(2)Sc(mu-OMe)(2)Sc(NO3)(2)(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. (C) 2008 Elsevier B.V. All rights reserved.",

author = "Cotton, {S A} and Fisher, {V M A} and Raithby, {P R} and S Schiffers and Teat, {S J}",

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journal = "Inorganic Chemistry Communications",

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T1 - Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex

AU - Cotton, S A

AU - Fisher, V M A

AU - Raithby, P R

AU - Schiffers, S

AU - Teat, S J

N1 - ID number: ISI:000257531200031

PY - 2008

Y1 - 2008

N2 - Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)(2)Sc(mu-OMe)(2)Sc(NO3)(2)(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. (C) 2008 Elsevier B.V. All rights reserved.

AB - Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)(2)Sc(mu-OMe)(2)Sc(NO3)(2)(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. (C) 2008 Elsevier B.V. All rights reserved.

UR - http://www.scopus.com/inward/record.url?scp=44749092576&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2008.04.007

DO - 10.1016/j.inoche.2008.04.007

M3 - Article

SN - 1387-7003

VL - 11

SP - 822

EP - 824

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex

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Senior Fellowship - TIME RESOLVED CRYSTALLOGRAPHY

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Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex

Abstract

Bibliographical note

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Senior Fellowship - TIME RESOLVED CRYSTALLOGRAPHY

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