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Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)(2)Sc(mu-OMe)(2)Sc(NO3)(2)(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. (C) 2008 Elsevier B.V. All rights reserved.
Cotton, S. A., Fisher, V. M. A., Raithby, P. R., Schiffers, S., & Teat, S. J. (2008). Synthesis and structure of a dimeric scandium bis(mu-methoxy) complex. Inorganic Chemistry Communications, 11(7), 822-824. https://doi.org/10.1016/j.inoche.2008.04.007