Synthesis and structural studies of diorganotin(IV)-based coordination polymers bearing silaalkylphosphonate ligands and their transformation into colloidal domains

R. Shankar; N. Singla; M. Asija; G. Kociok-Köhn; K.C. Molloy

doi:10.1021/ic500682t

Synthesis and structural studies of diorganotin(IV)-based coordination polymers bearing silaalkylphosphonate ligands and their transformation into colloidal domains

R. Shankar, N. Singla, M. Asija, G. Kociok-Köhn, K.C. Molloy

Indian Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Citations (SciVal)

Abstract

The contribution of silaalkylphosphonic acids Me₃SiCH₂ P(O)(OH)₂ (1) and Me₃SiC(CH₃) P(O)(OH)₂ (2) as ligands was demonstrated for the first time by the isolation of new diorganotin(IV) phosphonates Et₂Sn{OP(O)(OH)CH₂SiMe₃}(OSO₂Me) (3), (Et₂ Sn)₆{OPC(CH₃)₂SiMe₃}₄(OSOMe₂)₄ (4), and Et₂Sn(O3PCH₂SiMe₃) (5). X-ray crystallographic studies of 1-4 are presented. The structures of 1 and 2 adopt extended motifs by virtue of P-OH···O=P-type hydrogen bonding interactions. The molecular structure of 3 is composed of a dimer formed by bridging hydrogen phosphonate groups, while the sulfonate group appended on each tin atom acts in a μ₂-bridging mode to afford the formation of one-dimensional coordination polymer featuring alternate eight-membered [-Sn-O-P-O-]₂ and [-Sn-O-S-O-]₂ rings. The asymmetric unit of4 is composed of two crystallographically unique trinuclear tin phosphonate clusters with a Sn₃(μ₃-PO₃₎₂ core linked together by coordinative association of a μ₂-sulfonate group, while the remaining sulfonates are involved in the construction of a two-dimensional self-assembly. The identity of1-5 in solution was established by IR and multinuclear (¹H, ¹³C, ³¹P, ¹¹⁹Sn) NMR spectroscopy. The presence of silaalkyl group in5 imparts unusual solubility in hydrocarbon, aromatic, and ether solvents. As a consequence, the formation of colloidal particles of5 featuring rodlike morphology was achieved by ultrasonication of a solution in ethanol-chloroform mixture.

Original language	English
Pages (from-to)	6195-6203
Number of pages	9
Journal	Inorganic Chemistry
Volume	53
Issue number	12
Early online date	22 May 2014
DOIs	https://doi.org/10.1021/ic500682t
Publication status	Published - 16 Jun 2014

Access to Document

10.1021/ic500682t

Cite this

@article{9a92095efaae4d8e91cfd2b3f0ed37cc,

title = "Synthesis and structural studies of diorganotin(IV)-based coordination polymers bearing silaalkylphosphonate ligands and their transformation into colloidal domains",

abstract = "The contribution of silaalkylphosphonic acids Me3SiCH2 P(O)(OH)2 (1) and Me3SiC(CH3) P(O)(OH)2 (2) as ligands was demonstrated for the first time by the isolation of new diorganotin(IV) phosphonates Et2Sn{OP(O)(OH)CH2SiMe3}(OSO2Me) (3), (Et2 Sn)6{OPC(CH3)2SiMe3}4(OSOMe2)4 (4), and Et2Sn(O3PCH2SiMe3) (5). X-ray crystallographic studies of 1-4 are presented. The structures of 1 and 2 adopt extended motifs by virtue of P-OH···O=P-type hydrogen bonding interactions. The molecular structure of 3 is composed of a dimer formed by bridging hydrogen phosphonate groups, while the sulfonate group appended on each tin atom acts in a μ2-bridging mode to afford the formation of one-dimensional coordination polymer featuring alternate eight-membered [-Sn-O-P-O-]2 and [-Sn-O-S-O-]2 rings. The asymmetric unit of4 is composed of two crystallographically unique trinuclear tin phosphonate clusters with a Sn3(μ3-PO3)2 core linked together by coordinative association of a μ2-sulfonate group, while the remaining sulfonates are involved in the construction of a two-dimensional self-assembly. The identity of1-5 in solution was established by IR and multinuclear (1H, 13C, 31P, 119Sn) NMR spectroscopy. The presence of silaalkyl group in5 imparts unusual solubility in hydrocarbon, aromatic, and ether solvents. As a consequence, the formation of colloidal particles of5 featuring rodlike morphology was achieved by ultrasonication of a solution in ethanol-chloroform mixture.",

author = "R. Shankar and N. Singla and M. Asija and G. Kociok-K{\"o}hn and K.C. Molloy",

year = "2014",

month = jun,

day = "16",

doi = "10.1021/ic500682t",

language = "English",

volume = "53",

pages = "6195--6203",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Synthesis and structural studies of diorganotin(IV)-based coordination polymers bearing silaalkylphosphonate ligands and their transformation into colloidal domains

AU - Shankar, R.

AU - Singla, N.

AU - Asija, M.

AU - Kociok-Köhn, G.

AU - Molloy, K.C.

PY - 2014/6/16

Y1 - 2014/6/16

N2 - The contribution of silaalkylphosphonic acids Me3SiCH2 P(O)(OH)2 (1) and Me3SiC(CH3) P(O)(OH)2 (2) as ligands was demonstrated for the first time by the isolation of new diorganotin(IV) phosphonates Et2Sn{OP(O)(OH)CH2SiMe3}(OSO2Me) (3), (Et2 Sn)6{OPC(CH3)2SiMe3}4(OSOMe2)4 (4), and Et2Sn(O3PCH2SiMe3) (5). X-ray crystallographic studies of 1-4 are presented. The structures of 1 and 2 adopt extended motifs by virtue of P-OH···O=P-type hydrogen bonding interactions. The molecular structure of 3 is composed of a dimer formed by bridging hydrogen phosphonate groups, while the sulfonate group appended on each tin atom acts in a μ2-bridging mode to afford the formation of one-dimensional coordination polymer featuring alternate eight-membered [-Sn-O-P-O-]2 and [-Sn-O-S-O-]2 rings. The asymmetric unit of4 is composed of two crystallographically unique trinuclear tin phosphonate clusters with a Sn3(μ3-PO3)2 core linked together by coordinative association of a μ2-sulfonate group, while the remaining sulfonates are involved in the construction of a two-dimensional self-assembly. The identity of1-5 in solution was established by IR and multinuclear (1H, 13C, 31P, 119Sn) NMR spectroscopy. The presence of silaalkyl group in5 imparts unusual solubility in hydrocarbon, aromatic, and ether solvents. As a consequence, the formation of colloidal particles of5 featuring rodlike morphology was achieved by ultrasonication of a solution in ethanol-chloroform mixture.

AB - The contribution of silaalkylphosphonic acids Me3SiCH2 P(O)(OH)2 (1) and Me3SiC(CH3) P(O)(OH)2 (2) as ligands was demonstrated for the first time by the isolation of new diorganotin(IV) phosphonates Et2Sn{OP(O)(OH)CH2SiMe3}(OSO2Me) (3), (Et2 Sn)6{OPC(CH3)2SiMe3}4(OSOMe2)4 (4), and Et2Sn(O3PCH2SiMe3) (5). X-ray crystallographic studies of 1-4 are presented. The structures of 1 and 2 adopt extended motifs by virtue of P-OH···O=P-type hydrogen bonding interactions. The molecular structure of 3 is composed of a dimer formed by bridging hydrogen phosphonate groups, while the sulfonate group appended on each tin atom acts in a μ2-bridging mode to afford the formation of one-dimensional coordination polymer featuring alternate eight-membered [-Sn-O-P-O-]2 and [-Sn-O-S-O-]2 rings. The asymmetric unit of4 is composed of two crystallographically unique trinuclear tin phosphonate clusters with a Sn3(μ3-PO3)2 core linked together by coordinative association of a μ2-sulfonate group, while the remaining sulfonates are involved in the construction of a two-dimensional self-assembly. The identity of1-5 in solution was established by IR and multinuclear (1H, 13C, 31P, 119Sn) NMR spectroscopy. The presence of silaalkyl group in5 imparts unusual solubility in hydrocarbon, aromatic, and ether solvents. As a consequence, the formation of colloidal particles of5 featuring rodlike morphology was achieved by ultrasonication of a solution in ethanol-chloroform mixture.

UR - http://www.scopus.com/inward/record.url?scp=84902455634&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1021/ic500682t

U2 - 10.1021/ic500682t

DO - 10.1021/ic500682t

M3 - Article

AN - SCOPUS:84902455634

SN - 0020-1669

VL - 53

SP - 6195

EP - 6203

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Synthesis and structural studies of diorganotin(IV)-based coordination polymers bearing silaalkylphosphonate ligands and their transformation into colloidal domains

Abstract

Access to Document

Other files and links

Fingerprint

Cite this