Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)

A ur Rehman; S Ali; G Kociok-Kohn; K C Molloy

doi:10.1016/j.molstruc.2009.08.012

Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)

A ur Rehman
, S Ali
, G Kociok-Kohn
, K C Molloy

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (SciVal)

Abstract

The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	56-60
Number of pages	5
Journal	Journal of Molecular Structure
Volume	937
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2009.08.012
Publication status	Published - Nov 2009

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title = "Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)",

abstract = "The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.",

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year = "2009",

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T1 - Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)

AU - ur Rehman, A

AU - Ali, S

AU - Kociok-Kohn, G

AU - Molloy, K C

PY - 2009/11

Y1 - 2009/11

N2 - The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.

AB - The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.

UR - https://www.scopus.com/pages/publications/70349785099

UR - http://dx.doi.org/10.1016/j.molstruc.2009.08.012

U2 - 10.1016/j.molstruc.2009.08.012

DO - 10.1016/j.molstruc.2009.08.012

M3 - Article

SN - 0022-2860

VL - 937

SP - 56

EP - 60

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)

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