TY - JOUR
T1 - Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)
AU - ur Rehman, A
AU - Ali, S
AU - Kociok-Kohn, G
AU - Molloy, K C
PY - 2009/11
Y1 - 2009/11
N2 - The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.
AB - The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.
UR - http://www.scopus.com/inward/record.url?scp=70349785099&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1016/j.molstruc.2009.08.012
U2 - 10.1016/j.molstruc.2009.08.012
DO - 10.1016/j.molstruc.2009.08.012
M3 - Article
SN - 0022-2860
VL - 937
SP - 56
EP - 60
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
IS - 1-3
ER -