Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic alpha-hydroxyketones, including the structures of Sn(maltol)(2), Sn(tropolone)(2), Zn(tropolone)(2), and Zn(hinokitiol)(2)

M C Barret; M F Mahon; K C Molloy; J W Steed; P Wright

doi:10.1021/ic0100368

Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic alpha-hydroxyketones, including the structures of Sn(maltol)(2), Sn(tropolone)(2), Zn(tropolone)(2), and Zn(hinokitiol)(2)

M C Barret, M F Mahon, K C Molloy, J W Steed, P Wright

Department of Chemistry

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Abstract

Zinc(II) and fin(II) derivatives of maltol (Hmalt), ethylmaltol (HEtmalt), tropolone (Htrop), hinokitiol (Hhino), and kojic acid (Hkoj) have been prepared and characterized, and the crystal structures of M(trop)(2) (M = Zn, Sri) Zn(hino)(2). EtOH, and Sn(malt)2 have been determined. The Zn(trop)2 is a polymeric structure in which tropolone has both a bridging And chelating role; zinc(hino) crystallizes as an ethanol adduct of which the structure is a dimeric fragment of the Zn(trop)2 polymer and in which each metal,is "capped" by a molecule of alcohol, The in complexes are notably air-stable despite adopting monomeric pseudo-tricronal-bipyramidal structures (SnO4E; E is a stereochemically active lone electron pair) in, which the ligands only chelate a single metal center.

Original language	English
Pages (from-to)	4384-4388
Number of pages	5
Journal	Inorganic Chemistry
Volume	40
Issue number	17
DOIs	https://doi.org/10.1021/ic0100368
Publication status	Published - 2001

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ID number: ISI:000170381600037

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Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic alpha-hydroxyketones, including the structures of Sn(maltol)(2), Sn(tropolone)(2), Zn(tropolone)(2), and Zn(hinokitiol)(2). / Barret, M C; Mahon, M F; Molloy, K C et al.
In: Inorganic Chemistry, Vol. 40, No. 17, 2001, p. 4384-4388.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic alpha-hydroxyketones, including the structures of Sn(maltol)(2), Sn(tropolone)(2), Zn(tropolone)(2), and Zn(hinokitiol)(2)",

abstract = "Zinc(II) and fin(II) derivatives of maltol (Hmalt), ethylmaltol (HEtmalt), tropolone (Htrop), hinokitiol (Hhino), and kojic acid (Hkoj) have been prepared and characterized, and the crystal structures of M(trop)(2) (M = Zn, Sri) Zn(hino)(2). EtOH, and Sn(malt)2 have been determined. The Zn(trop)2 is a polymeric structure in which tropolone has both a bridging And chelating role; zinc(hino) crystallizes as an ethanol adduct of which the structure is a dimeric fragment of the Zn(trop)2 polymer and in which each metal,is {"}capped{"} by a molecule of alcohol, The in complexes are notably air-stable despite adopting monomeric pseudo-tricronal-bipyramidal structures (SnO4E; E is a stereochemically active lone electron pair) in, which the ligands only chelate a single metal center.",

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T1 - Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic alpha-hydroxyketones, including the structures of Sn(maltol)(2), Sn(tropolone)(2), Zn(tropolone)(2), and Zn(hinokitiol)(2)

AU - Barret, M C

AU - Mahon, M F

AU - Molloy, K C

AU - Steed, J W

AU - Wright, P

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N2 - Zinc(II) and fin(II) derivatives of maltol (Hmalt), ethylmaltol (HEtmalt), tropolone (Htrop), hinokitiol (Hhino), and kojic acid (Hkoj) have been prepared and characterized, and the crystal structures of M(trop)(2) (M = Zn, Sri) Zn(hino)(2). EtOH, and Sn(malt)2 have been determined. The Zn(trop)2 is a polymeric structure in which tropolone has both a bridging And chelating role; zinc(hino) crystallizes as an ethanol adduct of which the structure is a dimeric fragment of the Zn(trop)2 polymer and in which each metal,is "capped" by a molecule of alcohol, The in complexes are notably air-stable despite adopting monomeric pseudo-tricronal-bipyramidal structures (SnO4E; E is a stereochemically active lone electron pair) in, which the ligands only chelate a single metal center.

AB - Zinc(II) and fin(II) derivatives of maltol (Hmalt), ethylmaltol (HEtmalt), tropolone (Htrop), hinokitiol (Hhino), and kojic acid (Hkoj) have been prepared and characterized, and the crystal structures of M(trop)(2) (M = Zn, Sri) Zn(hino)(2). EtOH, and Sn(malt)2 have been determined. The Zn(trop)2 is a polymeric structure in which tropolone has both a bridging And chelating role; zinc(hino) crystallizes as an ethanol adduct of which the structure is a dimeric fragment of the Zn(trop)2 polymer and in which each metal,is "capped" by a molecule of alcohol, The in complexes are notably air-stable despite adopting monomeric pseudo-tricronal-bipyramidal structures (SnO4E; E is a stereochemically active lone electron pair) in, which the ligands only chelate a single metal center.

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