Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

Edwin C. Constable; Andrew J. Edwards; Paul R. Raithby; Juan Soto; María JoséL Tendero; Ramón Martínez-Máñez

doi:10.1016/0277-5387(95)00101-W

Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

Edwin C. Constable, Andrew J. Edwards, Paul R. Raithby, Juan Soto, María JoséL Tendero, Ramón Martínez-Máñez

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.

Original language	English
Pages (from-to)	3061-3066
Number of pages	6
Journal	Polyhedron
Volume	14
Issue number	20-21
DOIs	https://doi.org/10.1016/0277-5387(95)00101-W
Publication status	Published - Sept 1995

Funding

Acknowledgements--We should like to thank the Schwei-zerischer Nationalfonds zur F6rderung der wis-senschaftlichen Forschung (Grant number: 21-37325.93), the Comisi6n Interministerial de Ciencia y Tecnologia (PB91-0807-CO2-02) and also the Ministerio de Educaci6n y Ciencia for support.

Funders	Funder number
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung	21-37325.93
Comisión Interministerial de Ciencia y Tecnología	PB91-0807-CO2-02

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Constable, E. C., Edwards, A. J., R. Raithby, P., Soto, J., Tendero, M. J., & Martínez-Máñez, R. (1995). Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine. Polyhedron, 14(20-21), 3061-3066. https://doi.org/10.1016/0277-5387(95)00101-W

Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine. / Constable, Edwin C.; Edwards, Andrew J.; R. Raithby, Paul et al.
In: Polyhedron, Vol. 14, No. 20-21, 09.1995, p. 3061-3066.

Research output: Contribution to journal › Article › peer-review

Constable, EC, Edwards, AJ, R. Raithby, P, Soto, J, Tendero, MJ & Martínez-Máñez, R 1995, 'Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine', Polyhedron, vol. 14, no. 20-21, pp. 3061-3066. https://doi.org/10.1016/0277-5387(95)00101-W

Constable EC, Edwards AJ, R. Raithby P, Soto J, Tendero MJ, Martínez-Máñez R. Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine. Polyhedron. 1995 Sept;14(20-21):3061-3066. doi: 10.1016/0277-5387(95)00101-W

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title = "Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine",

abstract = "The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.",

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AU - Constable, Edwin C.

AU - Edwards, Andrew J.

AU - R. Raithby, Paul

AU - Soto, Juan

AU - Tendero, María JoséL

AU - Martínez-Máñez, Ramón

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AB - The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.

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DO - 10.1016/0277-5387(95)00101-W

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Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

Abstract

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