Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

Edwin C. Constable; Andrew J. Edwards; Paul R. Raithby; Juan Soto; María JoséL Tendero; Ramón Martínez-Máñez

doi:10.1016/0277-5387(95)00101-W

Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

Edwin C. Constable, Andrew J. Edwards, Paul R. Raithby, Juan Soto, María JoséL Tendero, Ramón Martínez-Máñez

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.

Original language	English
Pages (from-to)	3061-3066
Number of pages	6
Journal	Polyhedron
Volume	14
Issue number	20-21
DOIs	https://doi.org/10.1016/0277-5387(95)00101-W
Publication status	Published - Sept 1995

Funding

Acknowledgements--We should like to thank the Schwei-zerischer Nationalfonds zur F6rderung der wis-senschaftlichen Forschung (Grant number: 21-37325.93), the Comisi6n Interministerial de Ciencia y Tecnologia (PB91-0807-CO2-02) and also the Ministerio de Educaci6n y Ciencia for support.

Funders	Funder number
Schwei-zerischer Nationalfonds zur F6rderung der wis-senschaftlichen Forschung	21-37325.93
Comisión Interministerial de Ciencia y Tecnología	PB91-0807-CO2-02

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0277-5387(95)00101-W

Fingerprint

Dive into the research topics of 'Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine'. Together they form a unique fingerprint.

Cite this

Constable, E. C., Edwards, A. J., R. Raithby, P., Soto, J., Tendero, M. J., & Martínez-Máñez, R. (1995). Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine. Polyhedron, 14(20-21), 3061-3066. https://doi.org/10.1016/0277-5387(95)00101-W

Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine. / Constable, Edwin C.; Edwards, Andrew J.; R. Raithby, Paul et al.
In: Polyhedron, Vol. 14, No. 20-21, 09.1995, p. 3061-3066.

Research output: Contribution to journal › Article › peer-review

Constable, EC, Edwards, AJ, R. Raithby, P, Soto, J, Tendero, MJ & Martínez-Máñez, R 1995, 'Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine', Polyhedron, vol. 14, no. 20-21, pp. 3061-3066. https://doi.org/10.1016/0277-5387(95)00101-W

Constable EC, Edwards AJ, R. Raithby P, Soto J, Tendero MJ, Martínez-Máñez R. Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine. Polyhedron. 1995 Sept;14(20-21):3061-3066. doi: 10.1016/0277-5387(95)00101-W

@article{2d9313d60ba4468b8a18b8c585499837,

title = "Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine",

abstract = "The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.",

author = "Constable, {Edwin C.} and Edwards, {Andrew J.} and {R. Raithby}, Paul and Juan Soto and Tendero, {Mar{\'i}a Jos{\'e}L} and Ram{\'o}n Mart{\'i}nez-M{\'a}{\~n}ez",

year = "1995",

month = sep,

doi = "10.1016/0277-5387(95)00101-W",

language = "English",

volume = "14",

pages = "3061--3066",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "20-21",

}

TY - JOUR

T1 - Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

AU - Constable, Edwin C.

AU - Edwards, Andrew J.

AU - R. Raithby, Paul

AU - Soto, Juan

AU - Tendero, María JoséL

AU - Martínez-Máñez, Ramón

PY - 1995/9

Y1 - 1995/9

N2 - The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.

AB - The reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine at room temperature for 24 h results in the synthesis of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane instead of the expected enone or 1,5-dicarbonyl. The crystal structure of this compound has been determined by single-crystal X-ray methods. The complex is electroactive and exhibits a reversible iron(II)/(III) process at +0.014 V vs ferrocene.

UR - http://www.scopus.com/inward/record.url?scp=0011977465&partnerID=8YFLogxK

U2 - 10.1016/0277-5387(95)00101-W

DO - 10.1016/0277-5387(95)00101-W

M3 - Article

AN - SCOPUS:0011977465

SN - 0277-5387

VL - 14

SP - 3061

EP - 3066

JO - Polyhedron

JF - Polyhedron

IS - 20-21

ER -

Synthesis and structural characterization of 3,5-[1,1′-ferrocenediyl]-1,7-dioxo-1,7-Di(2-pyridyl)-4-(2-pyridylcarbonyl)heptane; an unexpected compound obtained from the reaction of ferrocene-1,1′-dicarbaldehyde with 2-acetylpyridine

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this