Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor

Susumu Arimori; Matthew D Davidson; Thomas M Fyles; Thomas G Hibbert; Tony D James; Gabriele I Kociok-Kohn

doi:10.1039/b404937c

Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor

Susumu Arimori
, Matthew D Davidson
, Thomas M Fyles
, Thomas G Hibbert
, Tony D James
, Gabriele I Kociok-Kohn

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

108 Citations (SciVal)

Abstract

A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.

Original language	English
Pages (from-to)	1640-1641
Number of pages	2
Journal	Chemical Communications
Volume	14
DOIs	https://doi.org/10.1039/b404937c
Publication status	Published - 2004

Bibliographical note

Electronic supplementary information (ESI) available: synthetic and spectroscopic details for the preparation of 3; details of the fluorescence titration of 3 with F? including details on the procedure used for calculation of binding constants; and details of the crystal structure refinement. See http://www.rsc.org/suppdata/cc/b4/b404937c/

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10.1039/b404937c

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title = "Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor",

abstract = "A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.",

author = "Susumu Arimori and Davidson, \{Matthew D\} and Fyles, \{Thomas M\} and Hibbert, \{Thomas G\} and James, \{Tony D\} and Kociok-Kohn, \{Gabriele I\}",

note = "Electronic supplementary information (ESI) available: synthetic and spectroscopic details for the preparation of 3; details of the fluorescence titration of 3 with F? including details on the procedure used for calculation of binding constants; and details of the crystal structure refinement. See http://www.rsc.org/suppdata/cc/b4/b404937c/",

year = "2004",

doi = "10.1039/b404937c",

language = "English",

volume = "14",

pages = "1640--1641",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor

AU - Arimori, Susumu

AU - Davidson, Matthew D

AU - Fyles, Thomas M

AU - Hibbert, Thomas G

AU - James, Tony D

AU - Kociok-Kohn, Gabriele I

N1 - Electronic supplementary information (ESI) available: synthetic and spectroscopic details for the preparation of 3; details of the fluorescence titration of 3 with F? including details on the procedure used for calculation of binding constants; and details of the crystal structure refinement. See http://www.rsc.org/suppdata/cc/b4/b404937c/

PY - 2004

Y1 - 2004

N2 - A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.

AB - A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.

UR - http://dx.doi.org/10.1039/b404937c

U2 - 10.1039/b404937c

DO - 10.1039/b404937c

M3 - Article

SN - 1359-7345

VL - 14

SP - 1640

EP - 1641

JO - Chemical Communications

JF - Chemical Communications

ER -

Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor

Abstract

Bibliographical note

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