Synthesis and structural characterisation of an unsaturated osmium-gold cluster HOs3Au(CO)10(PR3) (R Et, Ph); x-ray crystal structures of HOs3Au(CO)10(PPh3) and Os3Au(CO)10(PPh3)(SCN)

Brian F.G. Johnson; David A. Kaner; Jack Lewis; Paul R. Raithby

doi:10.1016/S0022-328X(00)80141-2

Synthesis and structural characterisation of an unsaturated osmium-gold cluster HOs₃Au(CO)₁₀(PR₃) (R Et, Ph); x-ray crystal structures of HOs₃Au(CO)₁₀(PPh₃) and Os₃Au(CO)₁₀(PPh₃)(SCN)

Brian F.G. Johnson, David A. Kaner, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of [HOs₃(CO)₁₁]^- with AuClPR₃ (R Et, Ph) yields the complex HOs₃Au(CO)₁₀(PR₃), and the PPh₃ derivative has been characterised by an X-ray analysis; the structure is compared with that of Os₃Au(CO)₁₀(PPh₃)-(SCN) and is shown to contain a formally unsaturated OsOs bond.

Original language	English
Pages (from-to)	C33-C37
Journal	Journal of Organometallic Chemistry
Volume	215
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)80141-2
Publication status	Published - 28 Jul 1981

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)80141-2

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Synthesis and structural characterisation of an unsaturated osmium-gold cluster HOs₃Au(CO)₁₀(PR₃) (R Et, Ph); x-ray crystal structures of HOs₃Au(CO)₁₀(PPh₃) and Os₃Au(CO)₁₀(PPh₃)(SCN). / Johnson, Brian F.G.; Kaner, David A.; Lewis, Jack et al.
In: Journal of Organometallic Chemistry, Vol. 215, No. 2, 28.07.1981, p. C33-C37.

Research output: Contribution to journal › Article › peer-review

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abstract = "The reaction of [HOs3(CO)11]- with AuClPR3 (R Et, Ph) yields the complex HOs3Au(CO)10(PR3), and the PPh3 derivative has been characterised by an X-ray analysis; the structure is compared with that of Os3Au(CO)10(PPh3)-(SCN) and is shown to contain a formally unsaturated OsOs bond.",

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AU - Lewis, Jack

AU - Raithby, Paul R.

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AB - The reaction of [HOs3(CO)11]- with AuClPR3 (R Et, Ph) yields the complex HOs3Au(CO)10(PR3), and the PPh3 derivative has been characterised by an X-ray analysis; the structure is compared with that of Os3Au(CO)10(PPh3)-(SCN) and is shown to contain a formally unsaturated OsOs bond.

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Synthesis and structural characterisation of an unsaturated osmium-gold cluster HOs₃Au(CO)₁₀(PR₃) (R Et, Ph); x-ray crystal structures of HOs₃Au(CO)₁₀(PPh₃) and Os₃Au(CO)₁₀(PPh₃)(SCN)

Abstract

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