Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process

Dongmei Jiang; Luke L. Keenan; Andrew D. Burrows; Karen J. Edler

doi:10.1039/c2cc36344e

Synthesis and post-synthetic modification of MIL-101(Cr)-NH₂via a tandem diazotisation process

Dongmei Jiang, Luke L. Keenan, Andrew D. Burrows, Karen J. Edler

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Abstract

The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.

Original language	English
Pages (from-to)	12053-12055
Journal	Chemical Communications
Volume	48
Issue number	99
Early online date	17 Oct 2012
DOIs	https://doi.org/10.1039/c2cc36344e
Publication status	Published - 25 Dec 2012

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title = "Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process",

abstract = "The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.",

author = "Dongmei Jiang and Keenan, {Luke L.} and Burrows, {Andrew D.} and Edler, {Karen J.}",

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AU - Keenan, Luke L.

AU - Burrows, Andrew D.

AU - Edler, Karen J.

PY - 2012/12/25

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N2 - The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.

AB - The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.

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Synthesis and post-synthetic modification of MIL-101(Cr)-NH₂via a tandem diazotisation process

Abstract

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