Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process

Dongmei Jiang, Luke L. Keenan, Andrew D. Burrows, Karen J. Edler

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Abstract

The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.
Original languageEnglish
Pages (from-to)12053-12055
JournalChemical Communications
Volume48
Issue number99
Early online date17 Oct 2012
DOIs
Publication statusPublished - 25 Dec 2012

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Azo Compounds
Azo dyes
Aniline
Functional groups
Metals
MIL-101

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Synthesis and post-synthetic modification of MIL-101(Cr)-NH2via a tandem diazotisation process. / Jiang, Dongmei; Keenan, Luke L.; Burrows, Andrew D.; Edler, Karen J.

In: Chemical Communications, Vol. 48, No. 99, 25.12.2012, p. 12053-12055.

Research output: Contribution to journalArticle

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