Synthesis and crystal structure of Sb(N=CPh2)3

Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Christopher A. Russell; Dominic S. Wright

doi:10.1039/DT9930002257

Synthesis and crystal structure of Sb(N=CPh₂)₃

Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Christopher A. Russell, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Monomers of Sb(N=CPh₂)₃ 1, the first tris(imino) antimony compound characterised in the solid state, exhibit unusual packing in the crystal in which short aromatic meta-C-H ⋯ Sb intermonomer contacts are present.

Original language	English
Pages (from-to)	2257-2258
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/DT9930002257
Publication status	Published - 1993

ASJC Scopus subject areas

General Chemistry

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@article{f45ee7e4fca04349a1ad879ef8ab5529,

title = "Synthesis and crystal structure of Sb(N=CPh2)3",

abstract = "Monomers of Sb(N=CPh2)3 1, the first tris(imino) antimony compound characterised in the solid state, exhibit unusual packing in the crystal in which short aromatic meta-C-H ⋯ Sb intermonomer contacts are present.",

author = "Edwards, \{Andrew J.\} and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Russell, \{Christopher A.\} and Wright, \{Dominic S.\}",

year = "1993",

doi = "10.1039/DT9930002257",

language = "English",

pages = "2257--2258",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "14",

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T1 - Synthesis and crystal structure of Sb(N=CPh2)3

AU - Edwards, Andrew J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Russell, Christopher A.

AU - Wright, Dominic S.

PY - 1993

Y1 - 1993

N2 - Monomers of Sb(N=CPh2)3 1, the first tris(imino) antimony compound characterised in the solid state, exhibit unusual packing in the crystal in which short aromatic meta-C-H ⋯ Sb intermonomer contacts are present.

AB - Monomers of Sb(N=CPh2)3 1, the first tris(imino) antimony compound characterised in the solid state, exhibit unusual packing in the crystal in which short aromatic meta-C-H ⋯ Sb intermonomer contacts are present.

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U2 - 10.1039/DT9930002257

DO - 10.1039/DT9930002257

M3 - Article

AN - SCOPUS:37049076060

SN - 1472-7773

SP - 2257

EP - 2258

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 14

ER -

Synthesis and crystal structure of Sb(N=CPh₂)₃

Abstract

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