Synthesis and crystal and molecular structure of Os3(CO)9[1,1,1-tris(isocyanomethyl)ethane]: a novel tris-isocyanide ligand capped triosmium cluster

Edwin C. Constable; Brian F.G. Johnson; Fatima K. Khan; Jack Lewis; Paul R. Raithby; Patrizia Mikulcik

doi:10.1016/0022-328X(91)83111-G

Synthesis and crystal and molecular structure of Os₃(CO)₉[1,1,1-tris(isocyanomethyl)ethane]: a novel tris-isocyanide ligand capped triosmium cluster

Edwin C. Constable
, Brian F.G. Johnson
, Fatima K. Khan
, Jack Lewis
, Paul R. Raithby
, Patrizia Mikulcik

University of Cambridge
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of 1,1,1-tris(isocyanomethyl)ethane (trisNC) (3) with [Os₃(CO)₁₀(NCMe)₂] gives the tripod-capped cluster [Os₃(CO)₉(trisNC)] (4), which has been fully characterised by spectroscopic and X-ray crystallographic techniques.

Original language	English
Pages (from-to)	C15-C18
Journal	Journal of Organometallic Chemistry
Volume	403
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(91)83111-G
Publication status	Published - 12 Feb 1991

Funding

Acknowledgements. We thank the Association of Commonwealth Universities for financial support (F.K.) and Johnson Matthey p.1.c. for their generous loans of ruthenium and osmium salts.

Funders
The Association of Commonwealth Universities

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(91)83111-G

Cite this

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title = "Synthesis and crystal and molecular structure of Os3(CO)9[1,1,1-tris(isocyanomethyl)ethane]: a novel tris-isocyanide ligand capped triosmium cluster",

abstract = "Reaction of 1,1,1-tris(isocyanomethyl)ethane (trisNC) (3) with [Os3(CO)10(NCMe)2] gives the tripod-capped cluster [Os3(CO)9(trisNC)] (4), which has been fully characterised by spectroscopic and X-ray crystallographic techniques.",

author = "Constable, \{Edwin C.\} and Johnson, \{Brian F.G.\} and Khan, \{Fatima K.\} and Jack Lewis and Raithby, \{Paul R.\} and Patrizia Mikulcik",

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doi = "10.1016/0022-328X(91)83111-G",

language = "English",

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TY - JOUR

T1 - Synthesis and crystal and molecular structure of Os3(CO)9[1,1,1-tris(isocyanomethyl)ethane]

T2 - a novel tris-isocyanide ligand capped triosmium cluster

AU - Constable, Edwin C.

AU - Johnson, Brian F.G.

AU - Khan, Fatima K.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Mikulcik, Patrizia

PY - 1991/2/12

Y1 - 1991/2/12

N2 - Reaction of 1,1,1-tris(isocyanomethyl)ethane (trisNC) (3) with [Os3(CO)10(NCMe)2] gives the tripod-capped cluster [Os3(CO)9(trisNC)] (4), which has been fully characterised by spectroscopic and X-ray crystallographic techniques.

AB - Reaction of 1,1,1-tris(isocyanomethyl)ethane (trisNC) (3) with [Os3(CO)10(NCMe)2] gives the tripod-capped cluster [Os3(CO)9(trisNC)] (4), which has been fully characterised by spectroscopic and X-ray crystallographic techniques.

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U2 - 10.1016/0022-328X(91)83111-G

DO - 10.1016/0022-328X(91)83111-G

M3 - Article

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VL - 403

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