TY - JOUR
T1 - Synthesis and characterization of cyclotetrakis(μ-oxo-dimethylaminoethanolato-κN
T2 - κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide
AU - Alam, Naveed
AU - Shahid, Muhammad
AU - Mazhar, Muhammad
AU - Rauf, Muhammad Khawar
AU - Molloy, Kieran C.
AU - Gill, Rohama
PY - 2014/8/1
Y1 - 2014/8/1
N2 - Two new metal(II) complexes formulated as [ZnI(dmae)]4·2(C7H8) 1 and CdI2(Hdmae)2 2 have been synthesized by using N,N-dimethylaminoethanol, a N,O donor ligand and characterized by melting point, elemental analysis, FT-IR spectroscopy, mass spectrometry and single crystal X-ray diffraction analysis. Complex 1 crystallizes in tetragonal I4(1)/a space group with μ2-O bridge between zinc atoms. The zinc atom is four coordinated with Zn-O 1.9315(13) and 1.9606(14) Å. The complex 2 is mononuclear with distorted octahedral geometry around the Cd(II) and contains two bidentate chelating Hdmae ligands and two iodine atoms, with Cd-O and Cd-N distances of 2.498(2) and 2.400(2) Å, respectively, and the weak O-H⋯I hydrogen bonds like interactions link the molecules to generate a 1D supramolecular structure.
AB - Two new metal(II) complexes formulated as [ZnI(dmae)]4·2(C7H8) 1 and CdI2(Hdmae)2 2 have been synthesized by using N,N-dimethylaminoethanol, a N,O donor ligand and characterized by melting point, elemental analysis, FT-IR spectroscopy, mass spectrometry and single crystal X-ray diffraction analysis. Complex 1 crystallizes in tetragonal I4(1)/a space group with μ2-O bridge between zinc atoms. The zinc atom is four coordinated with Zn-O 1.9315(13) and 1.9606(14) Å. The complex 2 is mononuclear with distorted octahedral geometry around the Cd(II) and contains two bidentate chelating Hdmae ligands and two iodine atoms, with Cd-O and Cd-N distances of 2.498(2) and 2.400(2) Å, respectively, and the weak O-H⋯I hydrogen bonds like interactions link the molecules to generate a 1D supramolecular structure.
KW - Cadmium
KW - N,N-dimethylaminoethanol
KW - X-ray crystal structure determination
KW - Zinc
UR - http://www.scopus.com/inward/record.url?scp=84984817953&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1515/zkri-2013-1721
U2 - 10.1515/zkri-2013-1721
DO - 10.1515/zkri-2013-1721
M3 - Article
AN - SCOPUS:84984817953
SN - 2194-4946
VL - 229
SP - 573
EP - 578
JO - Zeitschrift fur Kristallographie - Crystalline Materials
JF - Zeitschrift fur Kristallographie - Crystalline Materials
IS - 8
ER -