Synthesis and characterization of cyclotetrakis(μ-oxo-dimethylaminoethanolato-κN

κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide

Naveed Alam, Muhammad Shahid, Muhammad Mazhar, Muhammad Khawar Rauf, Kieran C. Molloy, Rohama Gill

Research output: Contribution to journalArticle

Abstract

Two new metal(II) complexes formulated as [ZnI(dmae)]4·2(C7H8) 1 and CdI2(Hdmae)2 2 have been synthesized by using N,N-dimethylaminoethanol, a N,O donor ligand and characterized by melting point, elemental analysis, FT-IR spectroscopy, mass spectrometry and single crystal X-ray diffraction analysis. Complex 1 crystallizes in tetragonal I4(1)/a space group with μ2-O bridge between zinc atoms. The zinc atom is four coordinated with Zn-O 1.9315(13) and 1.9606(14) Å. The complex 2 is mononuclear with distorted octahedral geometry around the Cd(II) and contains two bidentate chelating Hdmae ligands and two iodine atoms, with Cd-O and Cd-N distances of 2.498(2) and 2.400(2) Å, respectively, and the weak O-H⋯I hydrogen bonds like interactions link the molecules to generate a 1D supramolecular structure.

Original languageEnglish
Pages (from-to)573-578
Number of pages6
JournalZeitschrift fur Kristallographie - Crystalline Materials
Volume229
Issue number8
DOIs
Publication statusPublished - 1 Aug 2014

Fingerprint

Deanol
Toluene
Iodides
Cadmium
cadmium
iodides
toluene
Atoms
Zinc
synthesis
zinc
Ligands
atoms
ligands
Metal complexes
Chelation
Iodine
X ray diffraction analysis
iodine
melting points

Keywords

  • Cadmium
  • N,N-dimethylaminoethanol
  • X-ray crystal structure determination
  • Zinc

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

Synthesis and characterization of cyclotetrakis(μ-oxo-dimethylaminoethanolato-κN : κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide. / Alam, Naveed; Shahid, Muhammad; Mazhar, Muhammad; Rauf, Muhammad Khawar; Molloy, Kieran C.; Gill, Rohama.

In: Zeitschrift fur Kristallographie - Crystalline Materials, Vol. 229, No. 8, 01.08.2014, p. 573-578.

Research output: Contribution to journalArticle

Alam, Naveed ; Shahid, Muhammad ; Mazhar, Muhammad ; Rauf, Muhammad Khawar ; Molloy, Kieran C. ; Gill, Rohama. / Synthesis and characterization of cyclotetrakis(μ-oxo-dimethylaminoethanolato-κN : κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide. In: Zeitschrift fur Kristallographie - Crystalline Materials. 2014 ; Vol. 229, No. 8. pp. 573-578.
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