Synthesis and characterization of a new group of exo-coordinating O2N2-donor macrocycles

Bahram Ghanbari; Barzin Safarkoopayeh; Reze Kia; Paul R. Raithby

doi:10.1071/CH15204

Synthesis and characterization of a new group of exo-coordinating O₂N₂-donor macrocycles

Bahram Ghanbari, Barzin Safarkoopayeh, Reze Kia, Paul R. Raithby

Department of Chemistry

Sharif University of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (SciVal)

Abstract

The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O₂N₂-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, ¹H, ¹³C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.

Original language	English
Pages (from-to)	273-278
Number of pages	6
Journal	Australian Journal of Chemistry
Volume	69
Issue number	3
DOIs	https://doi.org/10.1071/CH15204
Publication status	Published - 31 Aug 2015

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10.1071/CH15204

http://dx.doi.org/10.1071/CH15204

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title = "Synthesis and characterization of a new group of exo-coordinating O2N2-donor macrocycles",

abstract = "The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.",

author = "Bahram Ghanbari and Barzin Safarkoopayeh and Reze Kia and Raithby, \{Paul R.\}",

year = "2015",

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doi = "10.1071/CH15204",

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journal = "Australian Journal of Chemistry",

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T1 - Synthesis and characterization of a new group of exo-coordinating O2N2-donor macrocycles

AU - Ghanbari, Bahram

AU - Safarkoopayeh, Barzin

AU - Kia, Reze

AU - Raithby, Paul R.

PY - 2015/8/31

Y1 - 2015/8/31

N2 - The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.

AB - The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.

UR - https://www.scopus.com/pages/publications/84962513259

UR - http://dx.doi.org/10.1071/CH15204

U2 - 10.1071/CH15204

DO - 10.1071/CH15204

M3 - Article

AN - SCOPUS:84962513259

SN - 0004-9425

VL - 69

SP - 273

EP - 278

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 3

ER -

Synthesis and characterization of a new group of exo-coordinating O₂N₂-donor macrocycles

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