TY - JOUR
T1 - Synthesis and characterization of a new group of exo-coordinating O2N2-donor macrocycles
AU - Ghanbari, Bahram
AU - Safarkoopayeh, Barzin
AU - Kia, Reze
AU - Raithby, Paul R.
PY - 2015/8/31
Y1 - 2015/8/31
N2 - The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.
AB - The reaction of 15-18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1-4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.
UR - http://www.scopus.com/inward/record.url?scp=84962513259&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1071/CH15204
U2 - 10.1071/CH15204
DO - 10.1071/CH15204
M3 - Article
AN - SCOPUS:84962513259
SN - 0004-9425
VL - 69
SP - 273
EP - 278
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 3
ER -