Synthesis and characterisation of the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ4-η 2-CO)2(η5-C5Me5)]

John E. Davies; Saifun Nahar; Paul R. Raithby; Gregory P. Shields

doi:10.1039/a607394h

Synthesis and characterisation of the novel mixed-metal cluster [Ru₅Rh(CO)₁₂(μ-CO)(μ₄-η ²-CO)₂(η⁵-C₅Me₅)]

John E. Davies, Saifun Nahar, Paul R. Raithby, Gregory P. Shields

Durham University

Research output: Contribution to journal › Article › peer-review

17 Citations (SciVal)

Abstract

The reaction of the octahedral dianion [Ru₆(CO)₁₈]^2- with the dication [Rh(η⁵-C₅Me₅)(MeCN)₃] ²⁺ afforded the novel mixed-metal cluster [Ru₅Rh(CO)₁₂(μ-CO)(μ₄-η ²-CO)₂(η⁵-C₅Me₅)], which has been shown by an X-ray analysis to contain a bi-edge bridged tetrahedral framework, with the Rh(η⁵-C₅Me₅) unit at the apex of the tetrahedron, and two μ₄-η²-CO capping carbonyl ligands.

Original language	English
Pages (from-to)	13-14
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	1
DOIs	https://doi.org/10.1039/a607394h
Publication status	Published - 7 Jan 1997

ASJC Scopus subject areas

General Chemistry

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title = "Synthesis and characterisation of the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ4-η 2-CO)2(η5-C5Me5)]",

abstract = "The reaction of the octahedral dianion [Ru6(CO)18]2- with the dication [Rh(η5-C5Me5)(MeCN)3] 2+ afforded the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ4-η 2-CO)2(η5-C5Me5)], which has been shown by an X-ray analysis to contain a bi-edge bridged tetrahedral framework, with the Rh(η5-C5Me5) unit at the apex of the tetrahedron, and two μ4-η2-CO capping carbonyl ligands.",

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T1 - Synthesis and characterisation of the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ4-η 2-CO)2(η5-C5Me5)]

AU - Davies, John E.

AU - Nahar, Saifun

AU - Raithby, Paul R.

AU - Shields, Gregory P.

PY - 1997/1/7

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N2 - The reaction of the octahedral dianion [Ru6(CO)18]2- with the dication [Rh(η5-C5Me5)(MeCN)3] 2+ afforded the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ4-η 2-CO)2(η5-C5Me5)], which has been shown by an X-ray analysis to contain a bi-edge bridged tetrahedral framework, with the Rh(η5-C5Me5) unit at the apex of the tetrahedron, and two μ4-η2-CO capping carbonyl ligands.

AB - The reaction of the octahedral dianion [Ru6(CO)18]2- with the dication [Rh(η5-C5Me5)(MeCN)3] 2+ afforded the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ4-η 2-CO)2(η5-C5Me5)], which has been shown by an X-ray analysis to contain a bi-edge bridged tetrahedral framework, with the Rh(η5-C5Me5) unit at the apex of the tetrahedron, and two μ4-η2-CO capping carbonyl ligands.

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Synthesis and characterisation of the novel mixed-metal cluster [Ru₅Rh(CO)₁₂(μ-CO)(μ₄-η ²-CO)₂(η⁵-C₅Me₅)]

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