Synthesis and characterisation of the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ42-CO)25-C5Me5)]

John E. Davies, Saifun Nahar, Paul R. Raithby, Gregory P. Shields

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of the octahedral dianion [Ru6(CO)18]2- with the dication [Rh(η5-C5Me5)(MeCN)3] 2+ afforded the novel mixed-metal cluster [Ru5Rh(CO)12(μ-CO)(μ42-CO)25-C5Me5)], which has been shown by an X-ray analysis to contain a bi-edge bridged tetrahedral framework, with the Rh(η5-C5Me5) unit at the apex of the tetrahedron, and two μ42-CO capping carbonyl ligands.

Original languageEnglish
Pages (from-to)13-14
Number of pages2
JournalJournal of the Chemical Society - Dalton Transactions
Issue number1
DOIs
Publication statusPublished - 7 Jan 1997

ASJC Scopus subject areas

  • Chemistry(all)

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