Synthesis and characterisation of the hexanuclear bimetallic cluster, [{Ru2(CO)8} (μ4-Bi) {(μ-H)Ru 3(CO)10}]

Brian F. G. Johnson; Jack Lewis; Paul R. Raithby; Alan J. Whitton

doi:10.1039/C39880000401

Synthesis and characterisation of the hexanuclear bimetallic cluster, [{Ru₂(CO)₈} (μ₄-Bi) {(μ-H)Ru ₃(CO)₁₀}]

Brian F. G. Johnson
, Jack Lewis
, Paul R. Raithby
, Alan J. Whitton

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The bimetallic cluster [Ru₅H(CO)₁₈(μ₄- Bi)] has been prepared from the reaction of Bi(NO₃) _3·5H₂O and Na[Ru₃H(CO)₁₁] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a 'Ru₂(CO)₈' fragment connected to a 'Ru₃H(CO) ₁₀' fragment by a μ₄-bismuth atom with a pseudo-tetrahedral co-ordination geometry.

Original language	English
Pages (from-to)	401-402
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39880000401
Publication status	Published - 31 Dec 1988

ASJC Scopus subject areas

Molecular Medicine

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title = "Synthesis and characterisation of the hexanuclear bimetallic cluster, [\{Ru2(CO)8\} (μ4-Bi) \{(μ-H)Ru 3(CO)10\}]",

abstract = "The bimetallic cluster [Ru5H(CO)18(μ4- Bi)] has been prepared from the reaction of Bi(NO3) 3·5H2O and Na[Ru3H(CO)11] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a 'Ru2(CO)8' fragment connected to a 'Ru3H(CO) 10' fragment by a μ4-bismuth atom with a pseudo-tetrahedral co-ordination geometry.",

author = "Johnson, \{Brian F. G.\} and Jack Lewis and Raithby, \{Paul R.\} and Whitton, \{Alan J.\}",

year = "1988",

month = dec,

day = "31",

doi = "10.1039/C39880000401",

language = "English",

pages = "401--402",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Synthesis and characterisation of the hexanuclear bimetallic cluster, [{Ru2(CO)8} (μ4-Bi) {(μ-H)Ru 3(CO)10}]

AU - Johnson, Brian F. G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Whitton, Alan J.

PY - 1988/12/31

Y1 - 1988/12/31

N2 - The bimetallic cluster [Ru5H(CO)18(μ4- Bi)] has been prepared from the reaction of Bi(NO3) 3·5H2O and Na[Ru3H(CO)11] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a 'Ru2(CO)8' fragment connected to a 'Ru3H(CO) 10' fragment by a μ4-bismuth atom with a pseudo-tetrahedral co-ordination geometry.

AB - The bimetallic cluster [Ru5H(CO)18(μ4- Bi)] has been prepared from the reaction of Bi(NO3) 3·5H2O and Na[Ru3H(CO)11] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a 'Ru2(CO)8' fragment connected to a 'Ru3H(CO) 10' fragment by a μ4-bismuth atom with a pseudo-tetrahedral co-ordination geometry.

UR - https://www.scopus.com/pages/publications/37049084509

U2 - 10.1039/C39880000401

DO - 10.1039/C39880000401

M3 - Article

AN - SCOPUS:37049084509

SN - 0022-4936

SP - 401

EP - 402

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 5

ER -

Synthesis and characterisation of the hexanuclear bimetallic cluster, [{Ru₂(CO)₈} (μ₄-Bi) {(μ-H)Ru ₃(CO)₁₀}]

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