TY - JOUR
T1 - Synthesis and characterisation of the hexanuclear bimetallic cluster, [{Ru2(CO)8} (μ4-Bi) {(μ-H)Ru 3(CO)10}]
AU - Johnson, Brian F. G.
AU - Lewis, Jack
AU - Raithby, Paul R.
AU - Whitton, Alan J.
PY - 1988/12/31
Y1 - 1988/12/31
N2 - The bimetallic cluster [Ru5H(CO)18(μ4- Bi)] has been prepared from the reaction of Bi(NO3) 3·5H2O and Na[Ru3H(CO)11] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a 'Ru2(CO)8' fragment connected to a 'Ru3H(CO) 10' fragment by a μ4-bismuth atom with a pseudo-tetrahedral co-ordination geometry.
AB - The bimetallic cluster [Ru5H(CO)18(μ4- Bi)] has been prepared from the reaction of Bi(NO3) 3·5H2O and Na[Ru3H(CO)11] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a 'Ru2(CO)8' fragment connected to a 'Ru3H(CO) 10' fragment by a μ4-bismuth atom with a pseudo-tetrahedral co-ordination geometry.
UR - http://www.scopus.com/inward/record.url?scp=37049084509&partnerID=8YFLogxK
U2 - 10.1039/C39880000401
DO - 10.1039/C39880000401
M3 - Article
AN - SCOPUS:37049084509
SN - 0022-4936
SP - 401
EP - 402
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 5
ER -