Synthesis and characterisation of [M2(η5-C5H5) 2(CO)4(μ-PH2)(μ-H)] (M = Mo, W); a new route to μ-PH2 complexes involving novel activation of a bridging diphosphorus ligand

John E. Davies; Martin J. Mays; Paul R. Raithby; Gregory P. Shields; Peter K. Tompkin

doi:10.1039/a608219j

Synthesis and characterisation of [M₂(η⁵-C₅H₅) ₂(CO)₄(μ-PH₂)(μ-H)] (M = Mo, W); a new route to μ-PH₂ complexes involving novel activation of a bridging diphosphorus ligand

John E. Davies
, Martin J. Mays
, Paul R. Raithby
, Gregory P. Shields
, Peter K. Tompkin

Durham University

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

Reaction of the known diphosphorus complexes [M₂(η⁵-C₅H₅) ₂(CO)₄(μ,η²-P₂)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF₄ affords the new phosphido complexes [M₂(η⁵C₅H₅)₂(CO) ₄(μ-PH₂)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.

Original language	English
Pages (from-to)	361-362
Number of pages	2
Journal	Chemical Communications
Volume	1997
Issue number	4
DOIs	https://doi.org/10.1039/a608219j
Publication status	Published - 31 Dec 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/a608219j

Cite this

Synthesis and characterisation of [M₂(η⁵-C₅H₅) ₂(CO)₄(μ-PH₂)(μ-H)] (M = Mo, W); a new route to μ-PH₂ complexes involving novel activation of a bridging diphosphorus ligand. / Davies, John E.; Mays, Martin J.; Raithby, Paul R. et al.
In: Chemical Communications, Vol. 1997, No. 4, 31.12.1997, p. 361-362.

Research output: Contribution to journal › Article › peer-review

@article{5df4edec513e4c5180691db79cf39249,

title = "Synthesis and characterisation of [M2(η5-C5H5) 2(CO)4(μ-PH2)(μ-H)] (M = Mo, W); a new route to μ-PH2 complexes involving novel activation of a bridging diphosphorus ligand",

abstract = "Reaction of the known diphosphorus complexes [M2(η5-C5H5) 2(CO)4(μ,η2-P2)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF4 affords the new phosphido complexes [M2(η5C5H5)2(CO) 4(μ-PH2)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.",

author = "Davies, \{John E.\} and Mays, \{Martin J.\} and Raithby, \{Paul R.\} and Shields, \{Gregory P.\} and Tompkin, \{Peter K.\}",

year = "1997",

month = dec,

day = "31",

doi = "10.1039/a608219j",

language = "English",

volume = "1997",

pages = "361--362",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterisation of [M2(η5-C5H5) 2(CO)4(μ-PH2)(μ-H)] (M = Mo, W); a new route to μ-PH2 complexes involving novel activation of a bridging diphosphorus ligand

AU - Davies, John E.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Shields, Gregory P.

AU - Tompkin, Peter K.

PY - 1997/12/31

Y1 - 1997/12/31

N2 - Reaction of the known diphosphorus complexes [M2(η5-C5H5) 2(CO)4(μ,η2-P2)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF4 affords the new phosphido complexes [M2(η5C5H5)2(CO) 4(μ-PH2)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.

AB - Reaction of the known diphosphorus complexes [M2(η5-C5H5) 2(CO)4(μ,η2-P2)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF4 affords the new phosphido complexes [M2(η5C5H5)2(CO) 4(μ-PH2)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.

UR - https://www.scopus.com/pages/publications/0000151326

U2 - 10.1039/a608219j

DO - 10.1039/a608219j

M3 - Article

AN - SCOPUS:0000151326

SN - 1359-7345

VL - 1997

SP - 361

EP - 362

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Synthesis and characterisation of [M₂(η⁵-C₅H₅) ₂(CO)₄(μ-PH₂)(μ-H)] (M = Mo, W); a new route to μ-PH₂ complexes involving novel activation of a bridging diphosphorus ligand

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this