Synthesis and characterisation of [M2(η5-C5H5) 2(CO)4(μ-PH2)(μ-H)] (M = Mo, W); a new route to μ-PH2 complexes involving novel activation of a bridging diphosphorus ligand

John E. Davies; Martin J. Mays; Paul R. Raithby; Gregory P. Shields; Peter K. Tompkin

doi:10.1039/a608219j

Synthesis and characterisation of [M₂(η⁵-C₅H₅) ₂(CO)₄(μ-PH₂)(μ-H)] (M = Mo, W); a new route to μ-PH₂ complexes involving novel activation of a bridging diphosphorus ligand

John E. Davies, Martin J. Mays, Paul R. Raithby, Gregory P. Shields, Peter K. Tompkin

Durham University

Research output: Contribution to journal › Article › peer-review

27 Citations (SciVal)

Abstract

Reaction of the known diphosphorus complexes [M₂(η⁵-C₅H₅) ₂(CO)₄(μ,η²-P₂)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF₄ affords the new phosphido complexes [M₂(η⁵C₅H₅)₂(CO) ₄(μ-PH₂)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.

Original language	English
Pages (from-to)	361-362
Number of pages	2
Journal	Chemical Communications
Volume	1997
Issue number	4
DOIs	https://doi.org/10.1039/a608219j
Publication status	Published - 31 Dec 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a608219j

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Synthesis and characterisation of [M₂(η⁵-C₅H₅) ₂(CO)₄(μ-PH₂)(μ-H)] (M = Mo, W); a new route to μ-PH₂ complexes involving novel activation of a bridging diphosphorus ligand. / Davies, John E.; Mays, Martin J.; Raithby, Paul R. et al.
In: Chemical Communications, Vol. 1997, No. 4, 31.12.1997, p. 361-362.

Research output: Contribution to journal › Article › peer-review

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abstract = "Reaction of the known diphosphorus complexes [M2(η5-C5H5) 2(CO)4(μ,η2-P2)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF4 affords the new phosphido complexes [M2(η5C5H5)2(CO) 4(μ-PH2)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.",

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AU - Davies, John E.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Shields, Gregory P.

AU - Tompkin, Peter K.

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N2 - Reaction of the known diphosphorus complexes [M2(η5-C5H5) 2(CO)4(μ,η2-P2)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF4 affords the new phosphido complexes [M2(η5C5H5)2(CO) 4(μ-PH2)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.

AB - Reaction of the known diphosphorus complexes [M2(η5-C5H5) 2(CO)4(μ,η2-P2)] (M = Mo 1a, W 1b) with M′OH (M′ = Na, K) in thf-water followed by addition of HBF4 affords the new phosphido complexes [M2(η5C5H5)2(CO) 4(μ-PH2)(μ-H)] (M = Mo 3a, W 3b) in good yield; 3a is the subject of a single-crystal X-ray diffraction study.

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Synthesis and characterisation of [M₂(η⁵-C₅H₅) ₂(CO)₄(μ-PH₂)(μ-H)] (M = Mo, W); a new route to μ-PH₂ complexes involving novel activation of a bridging diphosphorus ligand

Abstract

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