Abstract
The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2 with an excess of dppa gives [Os3(CO)10(dppa)]3 (2) and [Os3(CO)10(dppa)]4 (3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.
Original language | English |
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Pages (from-to) | C28-C30 |
Journal | Journal of Organometallic Chemistry |
Volume | 397 |
Issue number | 2 |
DOIs | |
Publication status | Published - 6 Nov 1990 |
Funding
Acknowledgements. We thank the Nehru Trust for Cambridge University, Cambridge Commonwealth Trust (A.D.M.), the Royal Commission for the Exhibition of 1851 (W.T.W.) and the UK committee of Vice Chancellors and Principals (A.D.M. and W.T.W.) for the financial support.
Funders | Funder number |
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Nehru Trust for Cambridge University | |
UK committee of Vice Chancellors and Principals | |
Royal Commission for the Exhibition of 1851 | |
Cambridge Commonwealth Trust |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry