Sustainable Afterglow Room-Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics

Keliang Wan; Yingxiang Zhai; Shouxin Liu; Jian Li; Shujun Li; Bernd Strehmel; Zhijun Chen; Tony D. James

doi:10.1002/anie.202202760

Sustainable Afterglow Room-Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics

Keliang Wan, Yingxiang Zhai, Shouxin Liu, Jian Li, Shujun Li, Bernd Strehmel, Zhijun Chen, Tony D. James

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Long-lived afterglow room-temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca²⁺-crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H-type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca²⁺-crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti-counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long-lived afterglow RTP from sustainable phenolics.

Original language	English
Article number	e202202760
Journal	Angewandte Chemie - International Edition
Volume	61
Issue number	31
Early online date	7 Apr 2022
DOIs	https://doi.org/10.1002/anie.202202760
Publication status	Published - 1 Aug 2022

Bibliographical note

Funding Information:
This work was supported by the National Natural Science Foundation of China (31890774) and the Natural Science Funding of Heilong Jiang province for Excellent Young Scholar (YQ2020C017). T.D.J. wishes to thank the Royal Society for a Wolfson Research Merit Award and the Open Research Fund of the School of Chemistry and Chemical Engineering, Henan Normal University for support (2020ZD01). B.S. wishes to thank foreign talents program of Chinese Ministry of Science and Technology.

Funding Information:
This work was supported by the National Natural Science Foundation of China (31890774) and the Natural Science Funding of Heilong Jiang province for Excellent Young Scholar (YQ2020C017). T.D.J. wishes to thank the Royal Society for a Wolfson Research Merit Award and the Open Research Fund of the School of Chemistry and Chemical Engineering, Henan Normal University for support (2020ZD01). B.S. wishes to thank foreign talents program of Chinese Ministry of Science and Technology.

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

Funding

This work was supported by the National Natural Science Foundation of China (31890774) and the Natural Science Funding of Heilong Jiang province for Excellent Young Scholar (YQ2020C017). T.D.J. wishes to thank the Royal Society for a Wolfson Research Merit Award and the Open Research Fund of the School of Chemistry and Chemical Engineering, Henan Normal University for support (2020ZD01). B.S. wishes to thank foreign talents program of Chinese Ministry of Science and Technology.

Keywords

Afterglow Emission
Long Lifetime
Natural Phenolics
Sodium Alginate
Sustainability

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.202202760

angew-060422.PDF
This is the peer reviewed version of the following article: K. Wan, Y. Zhai, S. Liu, J. Li, S. Li, B. Strehmel, Z. Chen, T. D. James, Angew. Chem. Int. Ed. 2022, e202202760; Angew. Chem. 2022, e202202760., which has been published in final form at https://doi.org/10.1002/anie.202202760. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
Accepted author manuscript, 765 KB

Cite this

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abstract = "Long-lived afterglow room-temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca2+-crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H-type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca2+-crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti-counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long-lived afterglow RTP from sustainable phenolics.",

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N2 - Long-lived afterglow room-temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca2+-crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H-type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca2+-crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti-counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long-lived afterglow RTP from sustainable phenolics.

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Sustainable Afterglow Room-Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics

Abstract

Bibliographical note

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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