Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

Merle Arrowsmith; Michael S Hill; Gabriele Kociok-Kohn

doi:10.1021/om200028m

Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

Merle Arrowsmith, Michael S Hill, Gabriele Kociok-Kohn

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

59 Citations (SciVal)

Abstract

Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.

Original language	English
Pages (from-to)	1291-1294
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	6
DOIs	https://doi.org/10.1021/om200028m
Publication status	Published - 28 Mar 2011

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10.1021/om200028m

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title = "Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy",

abstract = "Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.",

author = "Merle Arrowsmith and Hill, {Michael S} and Gabriele Kociok-Kohn",

year = "2011",

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doi = "10.1021/om200028m",

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AU - Arrowsmith, Merle

AU - Hill, Michael S

AU - Kociok-Kohn, Gabriele

PY - 2011/3/28

Y1 - 2011/3/28

N2 - Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.

AB - Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.

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DO - 10.1021/om200028m

M3 - Article

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JO - Organometallics

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Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

Abstract

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Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

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Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

Abstract

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Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

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