Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

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Abstract

Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.
LanguageEnglish
Pages1291-1294
Number of pages4
JournalOrganometallics
Volume30
Issue number6
DOIs
StatusPublished - 28 Mar 2011

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Catalysis
catalysis
catalytic activity
Catalyst activity
isolation
Earth (planet)
retarding
methylidyne
Ligands
ligands

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Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy. / Arrowsmith, Merle; Hill, Michael S; Kociok-Kohn, Gabriele.

In: Organometallics, Vol. 30, No. 6, 28.03.2011, p. 1291-1294.

Research output: Contribution to journalArticle

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