Supported ionic liquid phase catalysis with supercritical flow

Ulrich Hintermair; Guoying Zhao; Catherine C. Santini; Mark J. Muldoon; David J. Cole-Hamilton

doi:10.1039/b616186c

Supported ionic liquid phase catalysis with supercritical flow

Ulrich Hintermair, Guoying Zhao, Catherine C. Santini, Mark J. Muldoon, David J. Cole-Hamilton

Department of Chemistry

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93 Citations (SciVal)

Abstract

Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.

Original language	English
Pages (from-to)	1462-1464
Journal	Chemical Communications
Volume	2007
Issue number	14
Early online date	31 Jan 2007
DOIs	https://doi.org/10.1039/b616186c
Publication status	Published - 2007

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title = "Supported ionic liquid phase catalysis with supercritical flow",

abstract = "Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.",

author = "Ulrich Hintermair and Guoying Zhao and Santini, \{Catherine C.\} and Muldoon, \{Mark J.\} and Cole-Hamilton, \{David J.\}",

year = "2007",

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AU - Hintermair, Ulrich

AU - Zhao, Guoying

AU - Santini, Catherine C.

AU - Muldoon, Mark J.

AU - Cole-Hamilton, David J.

PY - 2007

Y1 - 2007

N2 - Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.

AB - Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.

UR - http://dx.doi.org/10.1039/b616186c

U2 - 10.1039/b616186c

DO - 10.1039/b616186c

M3 - Article

SN - 1359-7345

VL - 2007

SP - 1462

EP - 1464

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Supported ionic liquid phase catalysis with supercritical flow

Abstract

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