Supported ionic liquid phase catalysis with supercritical flow

Ulrich Hintermair, Guoying Zhao, Catherine C. Santini, Mark J. Muldoon, David J. Cole-Hamilton

Research output: Contribution to journalArticle

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Abstract

Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.
Original languageEnglish
Pages (from-to)1462-1464
JournalChemical Communications
Volume2007
Issue number14
Early online date31 Jan 2007
DOIs
Publication statusPublished - 2007

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Ionic Liquids
Ionic liquids
Catalysis
Hydroformylation
Rhodium
Catalysts
Leaching
Gases
Substrates
1-octene

Cite this

Hintermair, U., Zhao, G., Santini, C. C., Muldoon, M. J., & Cole-Hamilton, D. J. (2007). Supported ionic liquid phase catalysis with supercritical flow. Chemical Communications, 2007(14), 1462-1464. https://doi.org/10.1039/b616186c

Supported ionic liquid phase catalysis with supercritical flow. / Hintermair, Ulrich; Zhao, Guoying; Santini, Catherine C.; Muldoon, Mark J.; Cole-Hamilton, David J.

In: Chemical Communications, Vol. 2007, No. 14, 2007, p. 1462-1464.

Research output: Contribution to journalArticle

Hintermair, U, Zhao, G, Santini, CC, Muldoon, MJ & Cole-Hamilton, DJ 2007, 'Supported ionic liquid phase catalysis with supercritical flow', Chemical Communications, vol. 2007, no. 14, pp. 1462-1464. https://doi.org/10.1039/b616186c
Hintermair, Ulrich ; Zhao, Guoying ; Santini, Catherine C. ; Muldoon, Mark J. ; Cole-Hamilton, David J. / Supported ionic liquid phase catalysis with supercritical flow. In: Chemical Communications. 2007 ; Vol. 2007, No. 14. pp. 1462-1464.
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